MACROBICYCLIC (HEXAAMINE)PLATINUM(IV) COMPLEXES: SYNTHESIS, CHARACTERIZATION, AND ELECTROCHEMISTRY.

被引：0
|
作者：
Boucher, Heather A.
Lawrance, Geoffrey A.
Lay, Peter A.
Sargeson, Alan M.
Bond, Alan M.
Sangster, David F.
Sullivan, James C.
机构：
来源：
Journal of the American Chemical Society | 1983年 / 105卷 / 14期
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D O I：
暂无
中图分类号：
O6 [化学]; TQ [化学工业];
学科分类号：
0703 ; 0817 ;
摘要：
Synthesis based on the reaction of Pt(en)//3**4** plus with formaldehyde, and ammonia or nitromethane, yielded the macrobicyclic complexes. . These complexes are substitution-inert diamagnetic octahedral ions and were characterized by X-ray crystallographic analysis of the Pt(sep)**4** plus by absorption and NMR spectroscopy. Addition of an electron to the Pt(IV) complexes, radiolytically or electrochemically, yielded transient monomeric macrobicyclic Pt(III)ions.
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页码：4652 / 4661
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