Rhodium and iridium complexes derived from trans-[MCl(CO)(PPh3)2] (M = Rh, Ir) and pyridine-2-thiolate or 4,6-dimethylpyrimidine-2-thiolate ligands: S-monodentate coordination versus S,N-chelation and S,N-bridging; reactivity of trans-[Ir('Spy')(CO)(PPh3)2] and trans-[Ir('SpymMe2')(CO)(PPh3)2] towards acid

被引：0

作者：

Dahlenburg, Lutz ^{[1
]}

Kühnlein, Michael ^{[1
]}

机构：

[1] Inst. für Anorganische Chemie, Univ. Erlangen-Nürnberg, Egerlandstrasse 1, D-91058 Erlangen, Germany

来源：

| 2000年 / Wiley-VCH Verlag卷

关键词：

Bridging ligands - Chelate - Chelate complex - Metal centres - Protonations - Pyridine-2 - Rhodium and iridium complexes - S ligands - Thiolate ligands - Thiolates;

D O I：

10.1002/1099-0682(200009)2000:93.0.co;2-v

中图分类号：

学科分类号：

摘要：

引用

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[1] Rhodium and iridium complexes derived from trans-[MCl(CO)(PPh3)2] (M = Rh, Ir) and pyridine-2-thiolate or 4,6-dimethylpyrimidine-2-thiolate ligands:: S-monodentate coordination versus S,N-chelation and S,N-bridging;: Reactivity of trans-[Ir('Spy')(CO)(PPh3)2] and trans[Ir('SpymMe2')(CO)(PPh3)2] towards acid
Dahlenburg, L
Kühnlein, M
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2000, (09) : 2117 - 2125
[2] Computational studies on the stabilities of trans-[Ir(OMe)(CO)(PPh3)2] and trans-[Ir(CH2Me)(CO)(PPh3)2] toward β-H elimination
Macgregor, Stuart A.
Vadivelu, Prabha
ORGANOMETALLICS, 2007, 26 (15) : 3651 - 3659
[3] TRANS-[IR(AR)(CO)(PPH3)2] TYPE ARYL COMPLEXES
DAHLENBURG, L
NAST, R
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 110 (03) : 395 - 406
[4] CARBONYLATION OF METAL OXYGEN BONDS - FORMATION OF CARBALKOXYDICARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM, MEOC(O)IR(CO)2(PPH3)2, (N-PROC(O)IR(CO)2(PPH3)2, (PHOC(O)IR(CO)2(PPH3)2, BY CARBONYLATION OF TRANS-ALKOXYCARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM, TRANS-MEOIR(CO)(PPH3)2, N-PROIR(CO)(PPH3)2, PHOIR(CO)(PPH3)2
REES, WM
ATWOOD, JD
ORGANOMETALLICS, 1985, 4 (02) : 402 - 404
[5] SYNTHESIS AND REACTIVITY OF TRANS-REF(CO)3(PPH3)2 AND TRANS-(ME3SIO)3VNRE(CO)3(PPH3)2
HOFFMAN, NW
PROKOPUK, N
ROBBINS, MJ
JONES, CM
DOHERTY, NM
INORGANIC CHEMISTRY, 1991, 30 (22) : 4177 - 4181
[6] THE OXIDATIVE ADDITION OF 1-HALOALKANES TO MONOMERIC TRANS-[RHCL(CO)(P-ARYL3)2], TRANS-[RHBR(CO)(P-ARYL3)2] AND DIMERIC TRANS-[RH(MU-CL)(CO)PPH3)]2, TRANS-[RH(MU-I)(CO)PPH3)]
HARTLEY, FR
MURRAY, SG
POTTER, DM
CHIPPERFIELD, JR
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 306 (01) : 133 - 138
[7] PREPARATION AND REACTIVITY OF TRANS-IR(CH2CN)(CO)(PPH3)2
ZECCHIN, S
ZOTTI, G
PILLONI, G
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 235 (03) : 353 - 367
[8] TRANS-IR(PPH3)2(CO)(NHAR) COMPLEXES - THEIR SYNTHESES, CHARACTERIZATION, AND REACTIONS WITH CO
RAHIM, M
AHMED, KJ
ORGANOMETALLICS, 1994, 13 (05) : 1751 - 1756
[9] PHOTOINDUCED OXIDATION OF COORDINATED LIGANDS IN TRANS-[RHCL(CO)(PPH3)2] - GENERATION OF A DECARBONYLATION AGENT
GEOFFROY, GL
DENTON, DA
KEENEY, ME
BUCKS, RR
INORGANIC CHEMISTRY, 1976, 15 (10) : 2382 - 2385
[10] DECOMPOSITION OF IRIDIUM ALKOXIDE COMPLEXES TRANS-MEOIR(CO)(PPH3)2 N-PROIR(CO)(PPH3)2, I-PROIR(CO)(PPH3)2 - EVIDENCE FOR BETA-ELIMINATION
BERNARD, KA
REES, WM
ATWOOD, JD
ORGANOMETALLICS, 1986, 5 (02) : 390 - 391

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