Passivity of lithium in organic solvents

被引：0
|
作者：
Rahner, D. [1 ]
Machill, S. [1 ]
Siury, K. [1 ]
机构：
[1] Dresden Univ of Technology, Dresden, Germany
来源：
Journal of Power Sources | 1997年 / 68卷 / 1 pt 1期
关键词：
Electrolytes - Electrolytic reduction - Metallic films - Organic solvents - Passivation - Phase interfaces - Reaction kinetics;
D O I：
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中图分类号：
学科分类号：
摘要：
A short overview concerning the nature of lithium `passivity' and the use of in situ techniques in lithium research will be given in order to emphasize the important role of the properties of the phase-boundary metal/electrolyte. The electrochemical behaviour of lithium is strongly influenced by the formation of a surface layer due to the reduction of the solvent and of the electrolyte. A kinetic model for the layer formation at uncovered lithium surfaces will be suggested.
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页码：69 / 74
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