SOL-GEL PROCESSING OF SILICA. II. THE ROLE OF THE CATALYST

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作者
Pope, E.J.A. [1 ]
Mackenzie, J.D. [1 ]
机构
[1] Univ of California, Los Angeles, CA,, USA, Univ of California, Los Angeles, CA, USA
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CATALYSTS - GLASS - SILICA GEL;
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摘要
In the sol-gel synthesis of silica, a silicon-containing raw material, a solvent, water, and a catalyst are utilized. By varying the catalyst, dramatic effects on gelation time, porosity, bulk and apparent density, and volume shrinkage on drying were observed. For example, porosities ranging from two to sixty-eight per cent can be obtained for dried and fired gels. Mechanisms for catalysis have been proposed for the catalysts considered.
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页码:185 / 198
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