Uebergangsmetallkomplexe mit Schwefelliganden CXXIV Koordination von C- und S-Liganden an Metall-Carben-Thiolat-Fragmente [M('S2C')] [M = NiII, PdII, PtII; 'S2C'2- = 1,3-Imidazolidinyl-N,N'-bis(2-benzolthiolat) (2-)]. [M(L)('S2C')]-Komplexe mit L = CN-, CH-3, COCH-3, CNBu, CR2, SH- und SR- (R = Et, Ph, o-C6H4NH2)2

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Sellmann, D.

Allmann, C.

Heinemann, F.

Knoch, F.

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Journal of Organometallic Chemistry | / 541卷 / 1-2期

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[1] Transition metal complexes with sulfur ligands .124. Coordination of C and S ligands on metal-carbene-thiolate fragments [M('S2C')] [M = Ni(II), Pd(II), Pt(II); 'S2C'(2-) = 1,3-imidazolidinyl-N,N'-bis-(2-benzenethiolate) (2-)]. [M(L) ('S2C')] complexes where L = CN-, CH3-, COCH3-, CNBu, CR2, SH- and SR- (R = Et, Ph, ortho-C6H4NH2)
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[2] Transition metal complexes with sulfur ligands.: 149 Mononuclear carbene dithiolate [Ni(NHX)('S2C')] complexes with HNX = HNPiPr3 or HNSPh2 coligands ('S2C'2-=1,3-imidazolidinyl-N,N'-bis(2-benzenethiolate) (2-))
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[5] Stability and bonding situation of electron-deficient transition-metal complexes.: Theoretical study of the CO-labilizing effect of ligands L in [W(CO)5L] (L = C2H2, NCH, N2, C2H4, OH2, SH2, NH3, F-, Cl-, OH-, SH-) and [W(CO)4L]2- (L2- = O2C2H22-, S2C2H22-) and the structure of the 16-valence-electron complexes [W(CO)4L] and [W(CO)3L]2-
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[6] The 16-electron dithiolene complexes (p-cymene)M[S2C2(B10H10)] (M = Ru, Os) containing both η6(p-cymene) and η2-(ortho-carborane-dithiolate):: adduct formation with Lewis bases, and X-ray crystal structures of (p-cymene)-Ru[S2C2(B10H10)](L) (L = PPh3) and {(p-cymene)-Ru[S2C2(B10H10)]}2(μ-LL) (LL = Ph2PCH2CH2PPh2 and N2H4)
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[7] STUDIES OF THE REACTIVITY OF BINARY THIOMOLYBDATES AND TERTIARY OXOTHIOMOLYBDATES TOWARD ELECTROPHILES - REACTIONS WITH DICARBOMETHOXYACETYLENE AND THE SYNTHESIS AND STRUCTURES OF THE [ET4N]2[MOO(L)2], ANTI-[ET4N]2[MO2O2S2(L)2], SYN-[PH4P]2[MO2O2S2(L)2].2DMF, [PH4P]2[MO(L)3].DMF.C6H6, AND [PH4P]2[MO2S2(L)4].2CH2CL2 COMPLEXES (L = 1,2-DICARBOMETHOXY-1,2-ETHYLENEDITHIOLATE)
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[8] REACTIVITY OF THE MO(O)(S) FUNCTIONAL-GROUP IN THE [(L)MO(O)(MU-S)2MO(O)(S)]N- DIMERIC THIOMOLYBDATE COMPLEXES (L=C5H5-, N=1-,S4(2-), N=2) AND IMPLICATIONS REGARDING THE FUNCTION OF XANTHINE-OXIDASE - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [(DMF)3MO(O)(MU-S)2MO(O)(S2)], [PH4P][(C5H5)MO(O)(MU-S)2MO(O)(S2)], [PH4P]2[(S4)MO(O)(MU-S)2MO(O)(S)], AND (ET4N)4([(S4)MO(O)(MU-S)2MO(O)(S)]2)
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[9] FUNCTIONALIZED 1,1-ETHENEDITHIOLATES AS LIGANDS .3. PALLADIUM(II) AND PLATINUM(II) COMPLEXES WITH FERROCENYL-SUBSTITUTED 1,1-ETHENEDITHIOLATE LIGANDS - CRYSTAL-STRUCTURE ANALYSES OF CIS-(PH(3)P)(2)M[S2C=CH-C(O)-(ETA(5)-C5H4)FE(ETA(5)-C5H5)] (M=PD,PT)
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[10] TRANSITION-METAL COMPLEXES WITH SULFUR LIGANDS .21. THIOLATO-AMINO COMPLEXES OF IRON(II) AND MOLYBDENUM(II) WITH [M(SNNS)]-UNITS AND CO, PME3, NO AND N2H4 COLIGANDS (SNNS=SC6H4N(R)C2H4N(R)C6H4S)2-, WHERE R=H AND CH3)
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