Pb1-xCaxTiO3 thin films with thickness in the 200-1000 nm range have been prepared by pulsed laser deposition on Pt/TiO2/SiO2/(100)Si substrates. 10% weight PbO-rich ceramic targets have been ablated with a KrF excimer laser. It has been found that the Ca concentration of the films remains close to its concentration in the target (x = 0.24). Optimized crystalline orientation is obtained using non sintered targets, on the other hand optimized tetragonality has been found in 600 nm thick films. The films show an asymmetric ferroelectric behavior.
机构:
Guangdong Univ Technol, Dept Math & Phys, Guangzhou 510090, Peoples R ChinaGuangdong Univ Technol, Dept Math & Phys, Guangzhou 510090, Peoples R China
Tang, XG
Zhou, QF
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机构:Guangdong Univ Technol, Dept Math & Phys, Guangzhou 510090, Peoples R China
Zhou, QF
Zhang, JX
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机构:Guangdong Univ Technol, Dept Math & Phys, Guangzhou 510090, Peoples R China