Structural analyses of clay-metal complex hybrid films by observation of optical second harmonic generation

被引：0
|
作者：
Kawamata, J. [1 ]
Ogata, Y. [1 ]
Yamagishi, A. [1 ]
Inoue, K. [1 ]
机构：
[1] Res. Inst. for Electronic Science, Hokkaido University, Sapporo 060-0812, Japan
来源：
Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics | 2000年 / 25卷 / 1-4期
关键词：
Clay - Complexation - Molecular orientation - Monolayers - Nonlinear optics - Organometallics - Second harmonic generation;
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学科分类号：
摘要：
We observed the optical second harmonic generation (SHG) from clay-metal complex hybrid films. The Langmuir-Blodgett films, having non-centrosymmetric molecular alignment, were prepared by forming a monolayer of tris(4,7-diphenyl-l,10-phenanthroline)ruthenium(II)-perchlorate onto an aqueous dispersion of a clay. The dependence of the SHG signal intensity on the condition of the sample preparation was examined. Based on the results, we have analyzed the characteristics of the molecular alignment in those films.
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页码：431 / 436
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