The use of carbodicarbene for bio-based polyester synthesis via ring-opening copolymerization of cyclic anhydrides and epoxides

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作者：
Jeong, Seung Yeon [1 ]
Kim, Minseop [2 ]
Kim, Kunou [1 ]
Kim, Hyunseok [2 ]
Kim, Yoonjin [2 ]
Seo, Jongcheol [2 ]
Lee, Eunsung [2 ,3 ]
Son, Kyung-sun [1 ]
机构：
[1] Department of Chemistry, Chungnam National University, Daejeon,34134, Korea, Republic of
[2] Department of Chemistry, Pohang University of Science and Technology, Pohang,37673, Korea, Republic of
[3] Department of Chemistry, Seoul National University, Seoul,08826, Korea, Republic of
来源：
European Polymer Journal | 1600年 / 218卷
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摘要：
Alternating ring-opening copolymerization (ROCOP) of epoxides and cyclic anhydrides was investigated using carbodicarbene (CDC) as a single-component organic initiator. CDC produced various polyesters with different combinations of monomers, including bio-based monomers. The synthesized polyesters exhibited narrow dispersity and a wide range of glass transition temperatures. Moreover, a diblock copolyester was synthesized using self-switchable polymerization (ROCOP of the cyclic anhydride/epoxide, and ring-opening polymerization of lactone) in a one-pot synthesis. The formation of a terpolymer product was confirmed by diffusion-ordered spectroscopy and thermal gravimetric analysis. © 2024 Elsevier Ltd
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