Mixed valency in hydrogen bonded 'dimers of dimers'

被引：0
|
作者：
机构：
[1] Wilkinson, Luke A.
[2] McNeill, Laura
[3] Meijer, Anthony J. H. M.
[4] Patmore, Nathan J.
来源：
Patmore, N.J. (n.patmore@sheffield.ac.uk) | 1723年 / American Chemical Society卷 / 135期
关键词：
Dimolybdenum quadruply bonded compounds containing a pendant lactam functional group form self-complementary hydrogen bonded 'dimers of dimers' in the solid-state and CH2Cl2 solutions. Electrochemical studies in CH2Cl2 show two consecutive one-electron redox processes corresponding to oxidation of the Mo24+ cores. Spectroelectrochemical studies on the 'dimers of dimers' show no evidence of intervalence charge transfer bands in the mixed valence radical cations formed by one-electron oxidation; indicating that they are examples of proton-coupled mixed valency. © 2013 American Chemical Society;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
相关论文
共 50 条
  • [1] Mixed Valency in Hydrogen Bonded 'Dimers of Dimers'
    Wilkinson, Luke A.
    McNeill, Laura
    Meijer, Anthony J. H. M.
    Patmore, Nathan J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (05) : 1723 - 1726
  • [2] Mixed Valency in Quadruple Hydrogen-Bonded Dimers of Bis(biimidazolate)dirhodium Complexes
    Jin-Long
    Matsuda, Yuki
    Uemura, Kazuhiro
    Ebihara, Masahiro
    INORGANIC CHEMISTRY, 2015, 54 (05) : 2331 - 2338
  • [3] Organic mixed valency in quadruple hydrogen-bonded triarylamine dimers bearing ureido pyrimidinedione moieties
    Tahara, Keishiro
    Nakakita, Tetsufumi
    Katao, Shohei
    Kikuchi, Jun-ichi
    CHEMICAL COMMUNICATIONS, 2014, 50 (95) : 15071 - 15074
  • [4] Effects of electronic structure changes on stabilisation of the mixed-valence state in hydrogen bonded "dimers of dimers"
    Patmore, Nathan J.
    Meijer, Anthony J. H. M.
    Wilkinson, Luke A.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [5] Fullerenes - Hydrogen-bonded dimers
    Freemantle, M
    CHEMICAL & ENGINEERING NEWS, 2001, 79 (05) : 13 - 13
  • [6] ROTATIONAL SPECTROSCOPY OF HYDROGEN-BONDED DIMERS
    LEGON, AC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1982, 184 (SEP): : 58 - PHYS
  • [7] Hydrogen-bonded dimers in dipyrrinones and acyldipyrrinones
    Huggins, MT
    Lightner, DA
    MONATSHEFTE FUR CHEMIE, 2001, 132 (02): : 203 - 221
  • [8] Anharmonicity modeling in hydrogen bonded solvent dimers
    Buczek, Aneta
    Broda, Malgorzata A.
    Kupka, Teobald
    Kelterer, Anne-Marie
    JOURNAL OF MOLECULAR LIQUIDS, 2021, 339
  • [9] Spurious proton transfer in hydrogen bonded dimers
    Bautista-Renedo, Joanatan
    Ireta, Joel
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2024, 26 (32) : 21468 - 21475
  • [10] Hydrogen bonded dimers of triurea derivatives of triphenylmethanes
    Rudzevich, Y
    Rudzevich, V
    Schollmeyer, D
    Thondorf, I
    Bohmer, V
    ORGANIC LETTERS, 2005, 7 (04) : 613 - 616
12345