A thermodynamic assessment of the Sb-Zn system

被引：0
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作者：
Li, Jing-Bo [1 ]
Record, Marie-Christine [2 ]
Tedenac, Jean-Claude [3 ]
机构：
[1] Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, P.O. Box 603, Beijing, 100080, China
[2] TECSEN, UMR CNRS 6122, Universite Paul Cezanne, Aix-Marseille III, Av. De l'Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France
[3] Laboratoire de Physico-chimie de la Matiere Condensee, UMR CNRS 5617, Universite Montpellier II, Place E. Bataillon, 34095 Montpellier Cedex 5, France
来源：
Journal of Alloys and Compounds | 2007年 / 438卷 / 1-2期
关键词：
The thermodynamic assessment is made for the Sb-Zn system using the CALPHAD approach (calculation of phase diagram). The liquid phase; the intermediate compounds of SbZn; Sb3Zn4 (three modifications of Ε; δ and δ′) and Sb2Zn3 (two modifications of η and ξ) and the terminal phases of rhombohedral-Sb and hcp-Zn are taken into consideration in this optimization. Liquid phase is described by a substitutional solution model with Redlich-Kister polynomials. The intermediate compounds are treated as stoichiometric. Two terminal phases are taken as unary phases according to literature. A set of self-consistent thermodynamic parameters is obtained and the calculated phase diagram and thermodynamic properties are presented and compared with experimental data obtained from literature. © 2006 Elsevier B.V. All rights reserved;
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页码：171 / 177
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