Research progress on iron-based catalysts for CO2 hydrogenation to long-chain linear α-olefins

被引:4
|
作者
Wang C. [1 ]
Zhang J.-L. [1 ]
Gao X.-H. [1 ]
Zhao T.-S. [1 ]
机构
[1] State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry & Chemical Engineering, Ningxia University, Yinchuan
关键词
CO[!sub]2[!/sub] hydrogenation; Fischer-Tropsch synthesis; iron-based catalysts; long-chain linear α-olefins;
D O I
10.1016/S1872-5813(22)60058-6
中图分类号
学科分类号
摘要
Long-chain linear α-olefins (LAOs) are important industrial chemicals, which are mainly obtained from petrochemical process. With the increased impact of the greenhouse effect globally, research on CO2 control and mitigation has attracted much attention. Fischer-Tropsch synthesis (FTS) provides an alternative route to obtain LAOs. In this paper, research progress on iron-based catalysts including the roles of promoters and supports for the process of CO2 hydrogenation to LAOs are analyzed. Key factors affecting the selectivity of LAOs are discussed. Challenges and possible solutions of the reaction are summarized, and an outlook for designing high-efficient iron-based catalysts is thus presented. © 2023 Science Press. All rights reserved.
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页码:67 / 84
页数:17
相关论文
共 88 条
  • [1] ZOU C N, XIONG B, XUE H Q, ZHENG D W, GE Z X, WANG Y, JIANG L Y, PAN S Q, WU S T., The role of new energy in carbon neutral[J], Pet Explor Dev, 48, 2, (2021)
  • [2] FANG K, LI C L, TANG Y Q, HE J J, SONG J N., China’s pathways to peak carbon emissions: New insights from various industrial sectors[J], Appl Energy, 306, (2022)
  • [3] LANG X D, HE X, LI Z M, HE L N., New routes for CO2 activation and subsequent conversion[J], Curr Opin Green Sustainable Chem, 7, (2017)
  • [4] SATTHAWONG R, KOIZUMI N, SONG C, PRASASSARAKICH P., Bimetallic Fe-Co catalysts for CO2 hydrogenation to higher hydrocarbons[J], Util, 3, 4, pp. 102-106, (2013)
  • [5] XUE L, ZHANG C J, WU J F, FAN Q Y, LIU Y, WU Y X, LI J X, ZHANG H, LIU F R, ZENG S H., Unveiling the reaction pathway on Cu/CeO<sub>2</sub> catalyst for electrocatalytic CO<sub>2</sub> reduction to CH<sub>4</sub>[J], Appl Catal B: Environ, 304, (2022)
  • [6] MIAO Z R, WANG Q L, ZHANG Y F, MENG L P, WANG X X., In situ construction of S-scheme AgBr/BiOBr heterojunction with surface oxygen vacancy for boosting photocatalytic CO<sub>2</sub> reduction with H<sub>2</sub>O[J], Appl Catal B: Environ, 301, (2022)
  • [7] GUO L S, CUI Y, LI H J, FANG Y, PRASERT R, WU J, YANG G, YONEYAMA Y, TSUBAKI N., Selective formation of linear-alpha olefins (LAOS) by CO<sub>2</sub> hydrogenation over bimetallic Fe/Co-Y catalyst[J], Catal Commun, 130, (2019)
  • [8] RA E C, KIM K Y, KIM E H, LEE H, AN K, LEE J S., Recycling carbon dioxide through catalytic hydrogenation: Recent key developments and perspectives[J], ACS Catal, 10, 19, pp. 11318-11345, (2020)
  • [9] ROY S, CHEREVOTAN A, PETER S C., Thermochemical CO2 hydrogenation to single carbon products: Scientific and technological challenges[J], ACS Energy Lett, 3, 8, (2018)
  • [10] GUO L S, SUN J, GE Q J, TSUBAKI N., Recent advances in direct catalytic hydrogenation of carbon dioxide to valuable C<sub>2+</sub> hydrocarbons[J], J Mater Chem A, 6, 46, pp. 23244-23262, (2018)