Effect of BN fiber on thermal conductivity and insulation properties of graphene nanoplatelets/polypropylene composites

被引:0
|
作者
Qin G. [1 ]
Zhang J. [1 ]
Xu Z. [1 ]
Jiang P. [1 ]
机构
[1] Faculty of Material and Energy, Guangdong University of Technology, Guangzhou
关键词
BN; Finite element analysis (FEA); Graphene; Polymer matrix composites; Thermal insulation;
D O I
10.13801/j.cnki.fhclxb.20190917.005
中图分类号
学科分类号
摘要
The BN fiber-graphene nanoplatelets/polypropylene (BN fiber-GNP/PP) high thermal conductivity electrical insulation composite was prepared by melt blending. The effects of BN fiber content and length on the thermal insulation properties of BN fiber-GNP/PP composites were investigated by finite element simulation, SEM, XRD and thermal conductivity test results. The results show that the increase of BN fiber content and length in BN fiber-GNP/PP composites can increase the range of GNP distribution and the contact probability of BN fiber with GNP. At 7wt% GNP content, the addition of 100 μm BN fiber at 20wt% makes the thermal conductivity of BN fiber-GNP/PP composites 4.2 times higher than PP, while the electrical insulation is slightly improved. The simulation results show that the addition of high content of 100 μm BN fiber tends to complete the thermal network of BN fiber-GNP/PP composites and reduce the area of local heat flux. Under the influence of the "synergistic effect" of flake GNP and fibrous BN two-phase filler, GNP and BN fibers form a special "dual network" structure as "islands" and "bridges", respectively. The BN fiber acts as a high thermal conductivity "bridge" to block the formation of conductive pathways between adjacent GNP. The thermal insulation properties of the BN fiber-GNP/PP composite are improved. © 2020, Editorial Office of Acta Materiae Compositae Sinica. All right reserved.
引用
收藏
页码:546 / 552
页数:6
相关论文
共 21 条
  • [1] Bel'skaya E.P., Postnikov V.M., Khusid B.M., Et al., Thermal conductivity of filled polymer compositions, Journal of Engineering Physics, 41, 3, pp. 992-998, (1981)
  • [2] Li B., Liu Y., Sun B., Et al., Properties and heat-conduction thermally conductive polymer mechanism of composites, CIESC Journal, 60, 10, pp. 2650-2655, (2009)
  • [3] Agrawal A., Satapathy A., Development of a heat conduction model and investigation on thermal conductivity enhancement of AlN/epoxy composites, Procedia Engineering, 51, pp. 573-578, (2013)
  • [4] Keamloglu S., Ozkoc G., Aytac A., Thermally conductive boron nitride/SEBS/EVA ternary composites: Processing and characterization, Polymer Composites, 31, 8, pp. 1398-1408, (2010)
  • [5] Xue Y., Jin X., Fan Y., Et al., Boron nitride quasi-nanoscale fibers: Controlled synthesis and improvement on thermal properties of PHA polymer, International Journal of Polymeric Materials and Polymeric Biomaterials, 63, 15, pp. 794-799, (2014)
  • [6] Yu W., Xie H., Yin L., Et al., Exceptionally high thermal conductivity of thermal grease: Synergistic effects of graphene and alumina, International Journal of Thermal Sciences, 91, pp. 76-82, (2015)
  • [7] Dai W., Yu J., Liu Z., Et al., Enhanced thermal conductivity and retained electrical insulation for polyimide composites with SiC nanowires grown on graphene hybrid fillers, Composites Part A: Applied Science and Manufacturing, 76, pp. 73-81, (2015)
  • [8] Yang S.Y., Lin W.N., Huang Y.L., Et al., Synergetic effects of graphene platelets and carbon nanotubes on the mechanical and thermal properties of epoxy composites, Carbon, 49, 3, pp. 793-803, (2011)
  • [9] Chang H.C., Tsai H.J., Lin W.Y., Et al., Hexagonal boron nitride coated carbon nanotubes: Interlayer polarization improved field emission, ACS Applied Materials & Interfaces, 7, 26, pp. 14456-14462, (2015)
  • [10] Zhou W.Y., Wang Z.J., Dong L.N., Et al., Research progress of polymer/BN thermal conductive composites, Synthetic Resin and Plastic, 32, 2, pp. 80-84, (2015)