Effects of nano nickel powders addition on flash pyrolysis of poly(ethylene glycol)

被引：0
|
作者：
Lin, Z.K. [1 ]
Li, S.F. [1 ]
机构：
[1] Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui 230026, China
来源：
European Polymer Journal | 2008年 / 44卷 / 03期
关键词：
Pure PEG and the mixture of PEG and nano nickel powders (PEG/n-Ni) were pyrolyzed at 500 °C for 5 min in N2 atmosphere. GC/MS and FTIR were employed to detect the volatile products. Some important regularity in the mass spectra of the PEG pyrolysis products was discovered; and 11 series of PEG pyrolysis products were identified. The experimental results show that the nano Ni powders evidently change the relative contents of each products series. The statistical results of the ratio of C-O cleavage to C-C cleavage; as well as the ratio of hydrogenation to dehydrogenation; indicate that nano Ni powders have remarkable effects on the bonds cleavage and free radicals annihilation. The process of hydrogenolysis and hydrogenation were propounded to explain the effects of nano Ni addition on PEG flash pyrolysis. © 2007 Elsevier Ltd. All rights reserved;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：645 / 652
相关论文
共 50 条
  • [1] Effects of nano nickel powders addition on flash pyrolysis of poly(ethylene glycol)
    Lin, Z. K.
    Li, S. F.
    EUROPEAN POLYMER JOURNAL, 2008, 44 (03) : 645 - 652
  • [2] Effect of nano Ni-Fe alloy addition on flash pyrolysis of poly(ethylene glycol)
    Lin, Z. K.
    Han, D. L.
    Li, S. F.
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2013, 99 : 117 - 121
  • [3] Effect of nano Ni-Fe alloy addition on flash pyrolysis of poly(ethylene glycol)
    Lin, Z.K. (zklin@wzmc.edu.cn), 1600, Elsevier B.V., Netherlands (99):
  • [4] Effects of adding nano metal powders on thermooxidative degradation of poly(ethylene glycol)
    Z. Lin
    X. Han
    T. Wang
    S. Li
    Journal of Thermal Analysis and Calorimetry, 2008, 91 : 709 - 714
  • [5] Effects of adding nano metal powders on thermooxidative degradation of poly(ethylene glycol)
    Lin, Z.
    Han, X.
    Wang, T.
    Li, S.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 91 (03) : 709 - 714
  • [6] Platelet graphite nanofibers synthesized by the pyrolysis of poly(ethylene glycol)/hydrochloric acid mixture and nickel catalyst
    Lin, Wang-Hua
    Li, Yuan-Yao
    NANOTECHNOLOGY 2011: ADVANCED MATERIALS, CNTS, PARTICLES, FILMS AND COMPOSITES, NSTI-NANOTECH 2011, VOL 1, 2011, : 174 - 176
  • [7] Non-Isothermal Crystallization Kinetics of Poly(ethylene glycol) and Poly(ethylene glycol)-B-Poly(ε-caprolactone) by Flash DSC Analysis
    Li, Xiaodong
    Zou, Meishuai
    Lei, Lisha
    Xi, Longhao
    POLYMERS, 2021, 13 (21)
  • [8] Effects of the poly(ethylene glycol) addition on the properties of gelatin films crosslinked with formaldehyde vapor
    Maeda, T
    Motoyoshi, H
    KOBUNSHI RONBUNSHU, 1997, 54 (03) : 138 - 143
  • [9] Field emission properties of tapered carbon nanotubes synthesized by the pyrolysis of poly(ethylene glycol) using a nickel catalyst
    Lin, Wang-Hua
    Li, Yuan-Yao
    DIAMOND AND RELATED MATERIALS, 2012, 22 : 124 - 127
  • [10] Dispersion of Nano TiO2 in Ethylene Glycol and Poly(ethylene terephthalate)
    Hao, Lifei
    Konagaya, Shigeji
    Yamada, Toshiro
    Tada, Kaoru
    Takemasa, Jiro
    Ito, Katsuya
    COMPOSITE INTERFACES, 2010, 17 (5-7) : 559 - 570
12345