Additive reaction of [60] fullerene and dehydroabietylaniine under microwave irradiation

被引：0
|
作者：
Gao, Jian
Lin, Zhong-Xiang
Deng, Hui-Min
Chen, Wen-Ting
机构：
[1] College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
[2] Instrumental Analysis and Research Center, Sun Yat-Sen University, Guangzhou 510275, China
来源：
Xiandai Huagong/Modern Chemical Industry | 2007年 / 27卷 / SUPPL. 1期
关键词：
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of C60 fullerene with dehydroabietylamine (C20H31N) by the cycloaddition of nitrene intermediate was carried out in the presence of Pb(OAc)4 in chlorobenzene at 130°C for 2 h under microwave irradiation and the atmosphere of N2. The new derivatives of C60 in a 59.4% yield (based on consumed C60) were, isolated by silica column chromatography and characterized by FT-IR, 13C NMR, 1H NMR, MALDI-TOF-MS, and it was found that the most of derivatives were mono-additions, there were a small amount of bis-additions. The reaction under microwave irradiation and conventional heated condition was compared, and the results showed that microwave irradiation could shorten the time of reaction and raise the yield of products.
引用
收藏
页码：266 / 268
相关论文
共 50 条
  • [1] Synthesis of new C60-donor dyads by reaction of pyrazolylhydrazones with [60]fullerene under microwave irradiation
    de la Cruz, P
    Díaz-Ortiz, A
    García, JJ
    Gómez-Escalonilla, MJ
    de la Hoz, A
    Langa, F
    TETRAHEDRON LETTERS, 1999, 40 (08) : 1587 - 1590
  • [2] Fullerene chemistry under microwave irradiation
    Langa, F
    de la Cruz, P
    Espíldora, E
    García, JJ
    Pérez, MC
    de la Hoz, A
    CARBON, 2000, 38 (11-12) : 1641 - 1646
  • [3] Addition reactions of fluoroalkanesulfonyl azides to [60] fullerene under thermal or microwave irradiation condition
    Wu, Ran
    Lu, Xiaoyong
    Zhang, Yun
    Zhang, Jianmin
    Xiong, Wanting
    Zhu, Shizheng
    TETRAHEDRON, 2008, 64 (47) : 10694 - 10698
  • [4] The Oxidation of Fullerene[C-60] using Several Oxidants under Microwave Irradiation
    Ko, Weon Bae
    Hwang, Sung Ho
    Ahn, Ju Hyun
    ELASTOMERS AND COMPOSITES, 2005, 40 (01): : 45 - 52
  • [5] [60]Fullerene-initiated bulk polymerization of N-vinylcarbazole under the microwave irradiation
    Chen, Y
    Wang, JX
    Zhang, DZ
    Cai, RF
    Yu, HX
    Su, CW
    Huang, ZE
    POLYMER, 2000, 41 (21) : 7877 - 7880
  • [6] REACTION OF [60]FULLERENE WITH EPOXIDES UNDER PHOTO-IRRADIATION: SYNTHESIS OF C60-FUSED TETRAHYDROFURAN DERIVATIVES
    Miao, Chun-Bao
    Tian, Zong-Yong
    Ruan, Xiao-Jiao
    Sun, Xiao-Qiang
    Yang, Hai-Tao
    HETEROCYCLES, 2011, 83 (07) : 1615 - 1620
  • [7] The Michael reaction under microwave irradiation
    Zhende, Liu
    Xuchang, He
    PROGRESS IN CHEMISTRY, 2006, 18 (09) : 1121 - 1129
  • [8] Synthesis of Fullerene (C60)-Silver Nanoparticles Using Neem Gum Extract Under Microwave Irradiation
    Vinay, S. P.
    BIONANOSCIENCE, 2021, 11 (01) : 1 - 7
  • [9] Synthesis of Fullerene (C60)-Silver Nanoparticles Using Neem Gum Extract Under Microwave Irradiation
    S. P. Vinay
    BioNanoScience, 2021, 11 : 1 - 7
  • [10] Cycloadditions to [60]fullerene using microwave irradiation: A convenient and expeditious procedure.
    delaCruz, P
    delaHoz, A
    Langa, F
    Illescas, B
    Martin, N
    TETRAHEDRON, 1997, 53 (07) : 2599 - 2608
12345