Hydrated silicate ionic liquids: Ionic liquids for silicate material synthesis

被引：0
|
作者：
Vandenabeele, Dries [1 ]
Doppelhammer, Nikolaus [1 ,2 ]
Radhakrishnan, Sambhu [1 ,3 ]
Chandran, C. Vinod [1 ,3 ]
Wangermez, Wauter [1 ]
Rais, Anjul [1 ]
Vandeurzen, Elisabeth [1 ]
Jakoby, Bernhard [2 ]
Kirschhock, Christine [1 ]
Breynaert, Eric [1 ,3 ]
机构：
[1] Centrum voor Oppervlakte chemie & Katalyse: Karakterisatie en Applicatie Team (COK-KAT), KU Leuven, Belgium
[2] Institute for Microelectronics and Microsensors - Johannes Kepler University Linz, Altenberger Straße 69, Linz,4040, Austria
[3] NMRCoRe - NMR/X-Ray Platform for Convergence Research, KU Leuven, Celestijnenlaan 200F Box 2461, Heverlee,3001, Belgium
来源：
Journal of Molecular Liquids | 2025年 / 417卷
基金：
奥地利科学基金会; 欧洲研究理事会;
关键词：
Hydration; -; Silicates; Synthesis; (chemical);
D O I：
10.1016/j.molliq.2024.126603
中图分类号：
学科分类号：
摘要：
The development of Hydrated Silicate Ionic Liquids, which are hypo-hydrated room temperature melts of alkali silicates, has created new opportunities for synthesizing porous silicate materials. Their discovery also allows to reinterpret the role of an ionic liquid for zeolite synthesis and offers unique opportunities to study crystallization in situ. The reduced complexity of HSILs together with a large space of achievable zeolitic phases and framework compositions, renders them excellent systems for modelling and computer simulations. This work summarizes the impact of alkalinity, hydration, and cation type on silicate speciation and provides physicochemical data spanning relevant temperatures and compositions for zeolite formation. The data is meant as a reference point to further accommodate and verify (computational) models. © 2024 Elsevier B.V.
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