Polymerization of itaconic acid initiated by a potassium persulfate/N,N-dimethylethanolamine system

被引：0

作者：

Velickovic, S.J. ^{[1
]}

Dzunuzovic, E.S. ^{[1
]}

Griffiths, P.C. ^{[2
]}

Lacik, I. ^{[3
]}

Filipovic, J. ^{[1
]}

Popovic, I.G. ^{[1
]}

机构：

[1] Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade, Serbia

[2] School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3TB, United Kingdom

[3] Polymer Institute, Slovak Academy of Sciences, Dubravska Cesta 9, 842 36 Bratislava, Slovakia

来源：

Journal of Applied Polymer Science | 2008年 / 110卷 / 05期

关键词：

The synthesis and characterization of poly (itaconic acid) (PIA) with a novel initiator/activator system is presented. The initiator in this system was potassium persulfate, whereas the activator was N,N-dimethylethanolamine (DMEA). PIA was synthesized in distilled water and in 0.1.M HCl at 40C with reaction times of 72 and 96 h. PIA was investigated with differential scanning calorimetry, gel permeation chromatography, and pulse gradient spin echo-NMR and compared to the same polymer synthesized in dioxane with 2,2-azobisiso- butyronitrile as the initiator. It was shown that, despite the fact that some residual DMEA remained in the system, the properties of the PIA polymerized in the aqueous phase were very similar to the dioxane-synthesized polymer, which will enable a faster, cheaper, and environmentally more acceptable polymerization of itaconic acid. © 2008 Wiley Periodicals, Inc;

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摘要：

Journal article (JA)

引用

页码：3275 / 3282

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