Orbital symmetry control of electronic coupling in a symmetrical, all-carbon-bridged mixed valence compound: Synthesis, spectroscopy, and electronic structure of [{Mo(dppe)(ν-C7H7)} 2(μ-C4)]n+ (n = 0, 1, or 2)

被引：0

作者：

Fitzgerald, Emma C. ^{[1
]}

Brown, Neil J. ^{[2
]}

Edge, Ruth ^{[3
]}

Helliwell, Madeleine ^{[1
]}

Roberts, Hannah N. ^{[1
]}

Tuna, Floriana ^{[1
]}

Beeby, Andrew ^{[2
]}

Collison, David ^{[3
]}

Low, Paul J. ^{[2
]}

Whiteley, Mark W. ^{[1
]}

机构：

[1] School of Chemistry, University of Manchester, Manchester M13 9PL, United Kingdom

[2] Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, United Kingdom

[3] EPSRC National Service for EPR Spectroscopy, School of Chemistry, University of Manchester, Manchester, M13 9PL, United Kingdom

来源：

Organometallics | 2012年 / 31卷 / 01期

关键词：

Compendex;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Electronic structure

引用

页码：157 / 169

共 50 条

[1] Orbital Symmetry Control of Electronic Coupling in a Symmetrical, All-Carbon-Bridged "Mixed Valence" Compound: Synthesis, Spectroscopy, and Electronic Structure of [{Mo(dppe)(η-C7H7)}2(μ-C4)]n+ (n=0, 1, or 2)
Fitzgerald, Emma C.
Brown, Neil J.
Edge, Ruth
Helliwell, Madeleine
Roberts, Hannah N.
Tuna, Floriana
Beeby, Andrew
Collison, David
Low, Paul J.
Whiteley, Mark W.
ORGANOMETALLICS, 2012, 31 (01) : 157 - 169
[2] Synthesis, spectroscopy and electronic structure of the vinylidene and alkynyl complexes [W(C=CHR)(dppe)(η-C7H7)]+ and [W(C≡CR)(dppe)(η-C7H7)]n+ (n=0 or 1)
Lancashire, Hannah N.
Brown, Neil J.
Carthy, Laura
Collison, David
Fitzgerald, Emma C.
Edge, Ruth
Helliwell, Madeleine
Holden, Mark
Low, Paul J.
McDouall, Joseph J. W.
Whiteley, Mark W.
DALTON TRANSACTIONS, 2011, 40 (06) : 1267 - 1278
[3] Synthesis, structure and redox chemistry of the aminoallenylidene complex [Mo{C=C=C(Me)NEt2}(dppe)(η-C7H7)][BPh4]
Alturaifi, Huriyyah A.
Gerriow, Hawa
Gluyas, Josef B. G.
Mjornstedt, Sebastian
Raftery, James
Low, Paul J.
Whiteley, Mark W.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 827 : 15 - 22
[4] A COMPARISON OF THE RATES OF INTRAMOLECULAR HYDROGEN MIGRATION IN THE MOLECULES [MO(ETA-C7H8)2]N+ TO GIVE [MO(ETA-C7H7)(ETA-C7H9)]N+, N = 0,1
GREEN, MLH
NEWMAN, PA
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (13) : 816 - 817
[5] A COMPARISON OF THE RATES OF INTRAMOLECULAR HYDROGEN MIGRATION IN THE MOLECULES [MO(ETA-C7H8)2]N+ TO GIVE [MO(ETA-C7H7)(ETA-C7H9)]N+, N = 0 OR 1 - CRYSTAL-STRUCTURES OF [MO(ETA-C7H8)2],[MO(ETA-C7H7)(ETA-C7H9)], AND [MO(ETA-C7H8)2][BF4]
GREEN, MLH
NEWMAN, PA
BANDY, JA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (02): : 331 - 343
[6] Metallacumulenylidene complexes in the cycloheptatrienyl molybdenum series [Mo{(C)n=CR2}L2(η-C7H7)]+ (n=0-2; L2 = P-donor ligand).: X-ray crystal structures of [Mo{C=C(H)Ph}{P(OMe)3}2(η-C7H7)][BF4] and [Mo(C=C=CPh2)(dppe)(η-C7H7)][PF6] and DFT investigation of cumulenylidene ligand orientations
Grime, Richard W.
Helliwell, Madeleine
Hussain, Zaffar I.
Lancashire, Hannah N.
Mason, Christopher R.
McDouall, Joseph J. W.
Mydlowski, Christopher M.
Whiteley, Mark W.
ORGANOMETALLICS, 2008, 27 (05) : 857 - 871
[7] Electronic structure and spectroscopy of the cycloheptatrienyl molybdenum halide complexes [MoBrL2(η-C7F7)]n+ (L2=2CO, n=0; L2=2,2′-bipyridyl, n=0 or 1)
Roberts, Kathryn A. E.
Brown, Neil J.
Roberts, Hannah N.
McDouall, Joseph J. W.
Low, Paul J.
Whiteley, Mark W.
POLYHEDRON, 2015, 86 : 89 - 97
[8] Spectroscopic Properties and Electronic Structure of the Cycloheptatrienyl Molybdenum Alkynyl Complexes [Mo(CCR)(Ph2PCH2CH2PPh2)(η-C7H7)n+ (n=0 or 1; R = But, Fc, CO2Me, or C6H4-4-X, X = NH2, OMe, Me, H, CHO, CO2Me)
Brown, Neil J.
Collison, David
Edge, Ruth
Fitzgerald, Emma C.
Helliwell, Madeleine
Howard, Judith A. K.
Lancashire, Hannah N.
Low, Paul J.
McDouall, Joseph J. W.
Raftery, James
Smith, Charlene A.
Yufit, Dmitry S.
Whiteley, Mark W.
ORGANOMETALLICS, 2010, 29 (05) : 1261 - 1276
[9] Synthesis and structure of the diynyl complexes [Mo(CCCCR)L2(η-C7H7)], L2 = chelate N- or P-donor ligand, R = SiMe3 or H:: X-ray crystal structures of [Mo(CCCCSiMe3)(2,2′-bipyridine)(η-C7H7)] and [Mo(CCCCH)(Ph2PCH2CH2PPh2)(η-C7H7)]
Lancashire, Hannah N.
Ahmed, Rezaul
Hague, Tracy L.
Helliwell, Madeleine
Hopgood, Gareth A.
Sharp, Leanne
Whiteley, Mark W.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (17) : 3617 - 3626
[10] The structure of the ligand tri(1-cyclohepta-2,4,6-trienyl)phosphane, P(C7H7)3, in the hexafluoroacetylacetonato copper(I) complexes, (hfac)Cu[P(C7H7)3]n (n=1, 2)
Herberhold, M
Milius, W
Akkus, N
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2004, 59 (08): : 843 - 849

← 1 2 3 4 5 →