Characterization of the Ligand Field in Pseudo-Octahedral Ni(II) Complexes of Pincer-Type Amido Ligands: Magnetism, Redox Behavior, Electronic Absorption and High-Frequency and -Field EPR Spectroscopy

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作者
Ortiz, Robert J. [1 ]
Shepit, Michael [2 ]
van Lierop, Johan [2 ]
Krzystek, J. [3 ]
Telser, Joshua [4 ]
Herbert, David E. [1 ]
机构
[1] Department of Chemistry and the Manitoba Institute for Materials, University of Manitoba, 144 Dysart Road, Winnipeg, Manitoba,R3T 2 N2, Canada
[2] Department of Physics and Astronomy, University of Manitoba, 31 A Sifton Rd, Winnipeg, Manitoba,R3T 2 N2, Canada
[3] National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida,32310, United States
[4] Department of Biological, Physical and Health Sciences, Roosevelt University, Chicago, Illinois,60605, United States
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Compilation and indexing terms; Copyright 2025 Elsevier Inc;
D O I
e202300446
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摘要
Absorption spectroscopy - Charge transfer - Density functional theory - Electron spin resonance spectroscopy - Excited states - Ground state - Inorganic compounds - Magnetometry - Nickel compounds - Paramagnetic resonance - Paramagnetism - Transition metals
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