Polydopamine-halloysite nanotubes modified stainless steel mesh and its oil-water separation performance

被引:0
|
作者
Ji S. [1 ]
Huang C. [1 ]
Cai P. [1 ]
Li S. [1 ]
Chen X. [1 ]
机构
[1] College of Chemical Engineering and Materials, Tianjing University of Science and Technology, Tianjing
关键词
halloysite nanotubes; micro-nano structure; oil-water separat; polydopamine; superhydrophilic/ underwater superoleophobic;
D O I
10.13801/j.cnki.fhclxb.20221201.002
中图分类号
学科分类号
摘要
The massive generation of industrial oily wastewater and the frequent occurrence of oil spills have caused efficient treatment of oily wastewater to emerge as a global challenge. A superhydrophilic/ underwater superoleophobic stainless mesh (PDA-HNTs/SSM) was conveniently fabricated by in-situ immersion of polydopamine (PDA) and halloysite nanotubes (HNTs) and used for oil-water spearation. The surface morphology, chemical composition and wettability of the modified SSM were analyzed by SEM, EDS, FTIR, XRD, XPS and contact Angle instrument. The results showed that the wettability and surface micro-nano hierarchical structure of PDA-HNTs/SSM can be controlled by immersion times of PDA-HNTs. PDA-HNTs/SSM obtained by immersion for 10 times had the best wetting performance, the contact angle underwater of dichloromethane was 157°, and the sliding Angle is less than 5°. Dimetylbenzene, cyclohexane, n-hexane, petroleum ether and dichloromethane were used for oil-water separation test. The separation efficiency of PDA-HNTs/SSM was more than 99%, and still maintained above 95.5% after 50 cycles. Moreover, after standing in 1 mol/L HCl, NaOH and NaCl solution for 7 days or rubbing with sandpaper for 10 m, PDA-HNTs/SSM still maintained stable underwater superhydrophobility and good oil-water separation ability. © 2023 Beijing University of Aeronautics and Astronautics (BUAA). All rights reserved.
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页码:5124 / 5133
页数:9
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共 36 条
  • [1] QIU L, ZHANG J X, GUO Z G, Et al., Asymmetric superwetting stainless steel meshes for on-demand and highly effective oil-water emulsion separation[J], Separation and Purification Technology, 273, (2021)
  • [2] LI L L, SHI Y B, HUANG Y, Et al., The effect of governance on industrial wastewater pollution in China[J], International Journal of Environmental Research and Public Health, 19, 15, (2022)
  • [3] XUE Z X, WANG S T, LIN L, Et al., A novel superhydrophilic and underwater superoleophobic hydrogel-coated mesh for oil/water separation[J], Advanced Materials, 23, 37, pp. 4270-4273, (2011)
  • [4] WANG Chunying, QI Bohao, LIU Changsong, Et al., Preparation of ZnO modified stainless steel mesh with controllable wettability and its oil-water separation performance[J], Acta Materiae Compositae Sinica, 39, 12, pp. 5827-5834, (2022)
  • [5] CHEN Di, HUANG Shan, YANG Yuanyuan, Et al., Preparation of superwetting γ-aminopropyltriethoxysilaneTiO<sub>2</sub> coated fabric and its water purification performances[J], Acta Materiae Compositae Sinica, 39, 10, pp. 4620-4630, (2022)
  • [6] XIONG W, LI L, QIAO F, Et al., Air superhydrophilic-superoleophobic SiO<sub>2</sub>-based coatings for recoverable oil/water separation mesh with high flux and mechanical stability[J], Journal of Colloid And Interface Science, 600, pp. 118-126, (2021)
  • [7] LIU Z, CAO R, WEI A F, Et al., Superflexible/superhydrophilic PVDF-HFP/CuO-nanosheet nanofibrous membrane for efficient microfiltration[J], Applied Nanoscience, 9, 8, pp. 1991-2000, (2019)
  • [8] ALGIERI C, DRIOLI E., Zeolite membranes: Synthesis and applications[J], Separation and Purification Technology, 278, (2021)
  • [9] HUANG X W, ZHANG S, XIAO W, Et al., Flexible PDA@ACNTs decorated polymer nanofiber composite with superhydrophilicity and underwater superoleophobicity for efficient separation of oil-in-water emulsion[J], Journal of Membrane Science, 614, (2020)
  • [10] YANG X, HE Y, ZENG G Y, Et al., Bio-inspired method for preparation of multiwall carbon nanotubes decorated superhydrophilic ploy(vinylidene fluoride) membrane for oil/water emulsion separation[J], Chemical Engineering Journal, 321, pp. 245-256, (2017)