Molecular thermodynamics for solubility of gas in binary liquid

被引：0
|
作者：
Yang F. [1 ]
Wang X. [1 ]
Chen Q. [2 ]
Tan H. [1 ]
机构：
[1] MOE Key Laboratory of Thermo-Fluid Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049, Shaanxi
[2] State Key Laboratory of Technology in Space Cryogenic Propellants, Beijing
来源：
Huagong Xuebao/CIESC Journal | 2019年 / 70卷
关键词：
Phase equilibria; Solubility; Thermodynamics;
D O I：
10.11949/0438-1157.20190592
中图分类号：
学科分类号：
摘要：
A molecular-thermodynamic theory has been developed for predicting the solubility of a sparingly soluble gas in a complex binary liquid mixture at 0.101325 MPa. The binary liquid mixtures contain associating and solvating components whose molecules form weak chemical compounds. The Gibbs energy for the mixing process is the sum of three isothermal steps. The partial molar excess Gibbs energy of the solute is represented by two contributions, chemical and physical. When experimental uncertainties are taken into account, the predicted solubility of nitrogen in the binary solvent is in good agreement with previously published experimental solubility data. © All Right Reserved.
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页码：62 / 69
页数：7
相关论文
共 30 条
  • [1] Prausnitz J.M., Lichtenthaler R.N., de Azevedo E.G., Molecular Thermodynamics of Fluid-phase Equilibria, pp. 352-378, (1999)
  • [2] Harris H.G., Prausnitz J.M., Thermodynamics of solutions with physical and chemical interactions. Solubility of Acetylene in Organic solvents, Ind. Eng. Chem. Fundam., 8, 2, pp. 180-188, (1969)
  • [3] Kretschmer C.B., Wiebe R., Thermodynamics of alcohol - hydrocarbon mixtures, J. Chem. Phys., 22, 10, pp. 1697-1701, (1954)
  • [4] Chen X.P., Wang L.L., Deng S., Et al., Equilibrium solubility and volumetric mass transfer coefficient of H<sub>2</sub> in turpentine at high pressure, Journal of Chemical Industry and Engineering (China), 54, 5, pp. 682-686, (2003)
  • [5] He C.H., Hou Y.J., Wu Z.L., Correlation of solubility of pure gases in non-volatile solvents, Journal of Chemical Industry and Engineering (China), 43, 2, pp. 178-183, (1992)
  • [6] He M.G., Bai L.H., Liu S.Q., Et al., Solubility and volumetric mass transfer coefficient of CO<sub>2</sub> in 1-pentanol, CIESC Journal, 68, 5, pp. 1780-1785, (2017)
  • [7] Hu D.D., Bao L., Liu T., Et al., Interaction between supercritial carbon dioxide-cosolvent and poly(vinyl acetate), CIESC Journal, 69, 2, pp. 555-562, (2018)
  • [8] Hu Y., Xu Y.N., Prausnitz J.M., Molecular thermodynamics of gas solubility (Ⅰ): Henry constant of gas in non-polar solvent, Journal of Chemical Industry and Engineering (China), 38, 1, pp. 22-38, (1987)
  • [9] Shen J.C., Li J.Q., Bao Q., Et al., Solubility of carbon dioxide in dimethylamine under pressure, Journal of Chemical Industry and Engineering (China), 39, 6, pp. 716-722, (1988)
  • [10] Sun J.Y., Jiang H., Jiang B.B., Et al., Solubility and volumetric mass transfer coefficient of ethylene and propylene in n-hexane solution of low molecular weight polyethylene, CIESC Journal, 60, 9, pp. 2153-2160, (2009)
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