The characteristics of hydrolytic residues of lignocelluloses waste conversion into hydrogen through a series of experiments were studied, observed and studied the effects of gasification temperature, catalytic temperature, particle size of catalyst, S/B on gas composition, hydrogen yield were observed. Comparing hydrolytic residues of lignocelluloses waste conversion into hydrogen with sawdust conversion into hydrogen, the CO and CO2 volume ratios reduces, the H2/CO ratio and the H2 content increase greatly, the high-yield of hydrogen. Under the experimental conditions examined, the results showed that higher gasification temperature, catalytic temperature, S/B and small particle size of catalyst contributes to higher hydrogen yield, gasification temperature and S/B have more contribution to higher hydrogen yield. There are a fitting parameter of gasification temperature, particle size of catalyst and S/B.