Co0.5Zn0.5Fe2O4modifiedresidualcarbonasanexcellentmicrowaveabsorber

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作者
Yuanchun Zhang [1 ,2 ]
Dacheng Ma [1 ]
Xingzhao Zhang [1 ]
Chuanlei Zhu [1 ]
Shengtao Gao [1 ,2 ]
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[1] School of Chemical and Blasting Engineering, Anhui University of Science and Technology
[2] Joint National-Local Engineering Research Centre for Safe and Precise Coal Mining, Anhui University of Science and
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摘要
Microwave absorbers have great potential for military and civil applications. Herein, Co0.5Zn0.5Fe2O4/residual carbon(CZFO/RC) composites have been successfully prepared using a hydrothermal method. RC was derived from coal gasification fine slag(CGFS) via pickling, which removes inorganic compounds. Multiple test means have been used to study the chemical composition, crystal structure, and micromorphology of the CZFO/RC composites, as well as their electromagnetic parameters and microwave absorption(MA) properties. The CZFO/RC composites exhibit excellent MA performance owing to their dielectric and magnetic losses. When the thickness of CZFO/RC-2(FeCl3·6H2O of 0.007 mol, ZnCl2 of 0.00175 mol, and CoCl2·6H2O of 0.00175 mol) is 1.20 mm, the minimum reflection loss(RLmin) is-56.24 d B, whereas at a thickness of 3.00mm and 6.34 GHz, RLmin is-45.96 d B and the maximum effective absorption bandwidth is 1.83 GHz(5.53–7.36 GHz). Dielectric loss includes interface and dipole polarizations, while magnetic loss includes current and remnant magnetic loss. CZFO/RC-2 exhibits high impedance matching, allowing microwave to enter the absorber. The computer simulation technology confirms that CZFO/RC-2 considerably decreases the radar cross-section. This study can be used to promote the use of CGFS as electromagnetic wave(EMW)-absorbing materials.
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页码:534 / 545
页数:12
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