Utilizing a range of techniques including multi-band light curves,softness ratio analysis,structure functions,rms spectra,cross-correlation functions,and ratios of spectra from different intervals,we present a comprehensive study of the complex X-ray spectral variability in Seyfert 1 galaxy Ark 120,through re-analyzing its six XMM-Newton observations taken between 2003 and 2014.We find a clear“softer-when-brighter”trend in the 2–10 ke V power-law component over long timescales,with this trend being timescale dependent,as it is much weaker on shorter timescales,similar to that previously detected in NGC 4051.Notably,a rare“harder-when-brighter”trend is observed during one exposure,indicating dynamic changes in the spectral variability behavior of the power-law component.This exceptional exposure,with the spectral variability indeed marked by a power-law pivoting at an unusually low energy of~2 ke V,suggests intricate variations in the thermal Comptonization processes within the corona.Furthermore,when the data below 2 ke V are included,we identify that the soft excess component adds significant complexity to the spectral variability,such as evidenced by a transition from“harder-when-brighter”to“softer-when-brighter”during another single exposure.Such extra complexity arises because the variability of the soft excess sometimes follows and sometimes does not follow the changes in the power-law component.Our findings underscore the necessity of applying multiple analytic techniques to fully capture the multifaceted spectral variability of AGNs.