The research on viscosity-temperature characteristics of the mixed slag of biomass and bituminous coal

被引:0
|
作者
Ji H.-S. [1 ]
Li Z.-Q. [2 ]
Zhou Y. [2 ]
Qi Y. [2 ]
He Z.-X. [1 ]
机构
[1] Institute of Energy Research, Jiangsu University, Zhenjiang
[2] School of Energy and Power Engineering, Jiangsu University, Zhenjiang
关键词
Bituminous coal mixed with biomass fuel; Fusibility characteristics; Gasification; Slag; Viscosity-temperature characteristics;
D O I
10.19906/j.cnki.JFCT.2021002
中图分类号
学科分类号
摘要
Shenhua bituminous coal and corn stalks were selected as experimental materials, and the effects of biomass blending ratio on the ash melting characteristics and viscosity-temperature characteristics of Shenhua bituminous ash in a weakly reducing atmosphere were studied. The mineral composition and micro-morphology of ash were detectd by XRD and SEM, and the phase and mineral transformation of ash at different temperatures were simulated by thermodynamic software FactSage. The results indicate that with the increase in corn stalks addition, the contents of high melting point quartz, anorthite and cordierite in ash decrease, and the content of low melting point potassium feldspar increases. Besides, the critical viscosity temperature (tcv), the lowest operation temperature (tlp) of ash and the viscosity of slag reach to the minimum values as the blending ratio of corn stalk to Shenhua coal is 20%. When the temperature arrives at 1255 ℃, the value of viscosity is less than 25 Pa·s, which can meet the liquid slag discharging requirements of the gasifier. Combining the Urbain homogeneous model with the Einstein-Roscoe heterogeneous model and using the FactSage software to calculate the liquid phase content at different temperatures, an empirical formula for the viscosity prediction of the corn stalks and Shenhua bituminous coal mixed gasification slag has been obtained. Copyright ©2021 Editorial Dept. of Journal of Fuel Chemistry and Technology. All rights reserved.
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页码:11 / 19
页数:8
相关论文
共 20 条
  • [1] CROMPTON P, WU Y., Energy consumption in China: Past trends and future directions[J], Energy Econ, 27, 1, pp. 195-208, (2005)
  • [2] WU Xiao-jiang, ZHANG Zhong-xiao, PIAO Gui-lin, KOBAYASHI Nobusuke, MORI Shigekatsu, ITATYA Yoshinori, Gasification characteristics of coal with high ash fusion temperature in lab-scale down-flow gasifier, J Combust Sci Technol, 15, 2, pp. 182-186, (2009)
  • [3] JIN Ze-hua, HU Rui-sheng, GONG Xue, HU Jia-nan, DU Juan, LIU Shu-sen, FU De-hui, LI Ying-tong, LI Qiang, Analysis and consideration of the standardization system of coal utilization technical conditions in the modern coal chemical industry[J], Coal Chem Ind, 44, 1, (2016)
  • [4] HAN Guang-yi, ZHU Zhi-ping, ZHANG Hai-xia, Effect of coal blending ratio and temperature on gasification characteristics, Chem Eng, 46, 4, pp. 64-68, (2018)
  • [5] XIA Guang-bi, PIAO Gui-lin, ZHANG Ju-bing, XIE Hao, LI Shuai, Research on co-gasification characteristics of biomass char and coal[J], J Chin Soc Power Eng, 35, 8, pp. 681-686, (2015)
  • [6] LIU Tao, CHEN Xue-li, LI De-xia, LIU Xia, LIANG Qin-feng, Blending ash fusion and viscosity-temperature characteristics of biomass and coal, J Chem Ind Eng, 63, 4, pp. 1217-1225, (2012)
  • [7] SEEBOLD S, WU G, MULLER M., The influence of crystallization on the flow of coal ash-slags[J], Fuel, 187, pp. 376-387, (2017)
  • [8] CHEN Xiao-dong, KONG Ling-xue, BAI Jin, BAI Zong-qing, LI Wen, Effect of Na<sub>2</sub>O on mineral transformation of coal ash under high temperature gasification condition, J Fuel Chem Technol, 44, 3, pp. 263-272, (2016)
  • [9] ZHOU Yong-gang, FAN Jian-yong, LI Pei, WANG Bing-hui, ZHAO Hong, Mineral transmutation of high alkali zhundong coal in ash melting process, J Zhejiang Univ Eng Sci, 49, 8, pp. 1559-1564, (2015)
  • [10] XU Jie, LI Shuai-dan, LIU Shuai-jun, Investigation on the ash properties of straw, J Eng Therm Energy Pow, 34, 12, pp. 137-154, (2019)