Luminous Performance and Site-occupation Effect of Sr2InP3O11:Eu3+ Red Phosphor

被引:0
|
作者
Liang L. [1 ]
Zhao S. [1 ]
Li G. [1 ]
Liu Y. [1 ]
Wang R. [1 ]
Cai G. [1 ]
机构
[1] School of Materials Science and Engineering, Central South University, Changsha
来源
基金
中国国家自然科学基金;
关键词
Eu[!sup]3+[!/sup] doped; luminescence property; phosphor; site occupation;
D O I
10.37188/CJL.20240065
中图分类号
学科分类号
摘要
Red phosphor is an important component to improve the color rendering index and reduce the color tem⁃ perature of white light emitting diode(LED). In this paper,we select Eu3+ with characteristic red emission as activa⁃ tor ions,and new phosphate Sr2InP3O11 is used as the phosphor host. A series of Sr2−xInP3O11∶xEu3+(simplified as S2−xIP3∶xEu3+)and Sr2In1−xP3O11∶xEu3+(simplified as S2I1−xP3∶xEu3+)phosphors were synthesized through high tem⁃ perature solid state reaction. The photoluminescence performance and the effect rule of cation sites(Sr sites and In sites)of phosphor were detailly studied by XRD,room and variable temperature PL spectra,quantum efficiency and fluorescence lifetime. The results show that these two types of phosphors can emit bright red light(dominating by 593 nm and 612 nm)under the radiation of 254 nm and 393 nm. In addition,these synthesized phosphors have aver⁃ age color stability and thermal stability,which indicates that they have certain development potential in the field of phosphor conversion white LED lighting and displaying. © 2024 Editorial Office of Chinese Optics. All rights reserved.
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页码:913 / 922
页数:9
相关论文
共 49 条
  • [1] XIA Z G, CHEN M Y,, Et al., Recent developments in the new inorganic solid-state LED phosphors[J], Dalton Trans, 45, 28, pp. 11214-11232, (2016)
  • [2] LI J H, YAN J,, WEN D W,, Et al., Advanced red phosphors for white light-emitting diodes[J], J. Mater. Chem. C, 4, 37, pp. 8611-8623, (2016)
  • [3] LUO X F, XIE R J., Recent progress on discovery of novel phosphors for solid state lighting[J], J. Rare Earths, 38, 5, pp. 464-473, (2020)
  • [4] JIN S L, HUANG H,, Et al., Compact ultrabroadband light-emitting diodes based on lanthanide-doped lead-free double perovskites[J], Light Sci. Appl, 11, 1, (2022)
  • [5] NAIR G B, SWART H C, DHOBLE S J., A review on the advancements in phosphor-converted light emitting diodes(pcLEDs):phosphor synthesis,device fabrication and characterization[J], Prog. Mater. Sci, 109, (2020)
  • [6] GUO Z W, JIANG H M, Et al., Manipulating alkali charge compensation to improve red fluorescence and thermosta⁃ bility in Ba<sub>5</sub>P<sub>6</sub>O<sub>20</sub>∶Eu<sup>3+</sup> phosphor[J], Appl. Mater. Today, 37, (2024)
  • [7] DARSHAN C,, ARJUN A, PREMKUMAR H B,, Et al., Tailoring robust luminescent-based BaSrY<sub>4</sub>O<sub>8</sub>∶Eu<sup>3+</sup> platform opens new avenues for screening diverge surface prompted cheiloscopy,WLED’s,and dosimetric applications[J], Mater. To⁃ day Sustain, 24, (2023)
  • [8] OTSUKA T, HAYAKAWA T., Eu<sup>3+</sup> site distribution and local distortion of photoluminescent Ca<sub>3</sub>WO<sub>6</sub>∶(Eu<sup>3+</sup> ,K<sup>+</sup>)double perovskites as high-color-purity red phosphors[J], Adv. Sci, 10, 31, (2023)
  • [9] PENG X, YANG W W,, LING D X, Et al., Preparation and luminescence properties of red Sr<sub>3</sub> LiSbO<sub>6</sub>∶Eu<sup>3+</sup> phosphor[J], Chin. J. Lumin, 42, 4, pp. 455-461, (2021)
  • [10] WANG S Y, Et al., Double perovskite Ca<sub>2</sub>LuTaO<sub>6</sub>∶Eu<sup>3+</sup> red-emitting phosphors:synthesis,structure and photoluminescence characteristics[J], J. Alloys Compd, 804, pp. 230-236, (2019)