Preparation of tetra-needle-like zinc oxide whiskers/natural rubber antibacterial medical composites

被引：0

作者：

Chen X. ^{[1
]}

Jian L. ^{[1
]}

Zhang R. ^{[1
]}

机构：

[1] College of Chemistry and Materials, Longyan University, Longyan

来源：

Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica | 2021年 / 38卷 / 08期

关键词：

Antibacterial properties; Mechanical properties; Medical composites; Natural rubber; Natural rubber latex; Tetra-needle-like zinc oxide whiskers;

D O I：

10.13801/j.cnki.fhclxb.20201102.001

中图分类号：

学科分类号：

摘要：

The sodium stearate-tetra-needle-like zinc oxide whiskers (T-ZnOw)/natural rubber (NR) antibacterial medical composites were prepared by introducing the sodium stearate-T-ZnOw ultrasonic dispersion into natural rubber latex (NRL) matrix. The comprehensive mechanical properties, antibacterial properties and thermal stability properties of the composites were systematically studied. The results show that when sodium stearate-T-ZnOw loading of 3wt%, the mechanical properties and thermal stability properties of the composites achieve optimum results. Compared with the pure NR, the shore a hardness, modulus at 300%, tensile strength, tear strength and elongation at break of composites are increased by 8.6%, 25.4%, 20.3%, 25.6% and 6.4%, respectively; The initial thermal degradation temperature (T0) and the termination thermal degradation temperature (Tf) of the composites are increased by 21.2℃ and 5.9℃. When the content of sodium stearate-T-ZnOw exceeds 3wt%, it can inhibit the growth of Escherichia coli, Staphylococcus aureus, Acinetobacter baumannii and Staphylococcus epidermidis in natural rubber latex. It can enter bacterial cells, resulting in cell wall damage, cell leakage, cell death. © 2021, Editorial Office of Acta Materiae Compositae Sinica. All right reserved.

引用

页码：2694 / 2705

页数：11

共 50 条

[1] PENG Z, KONG L, LI S, Et al., Self-assembled natural rubber/silica nanocomposites: Its preparation and characterization, Composites Science and Technology, 67, pp. 3130-3139, (2007)
[2] YAN N, WU J K, ZHAN Y H, Et al., Carbon nanotubes/carbon black synergistic reinforced natural rubber compo-sites, Plastics, Rubber and Composites, 38, pp. 290-296, (2009)
[3] CHEN X, HU Z, ZHANG F, Et al., Natural rubber/tetra-needle-like zinc oxide whisker composites: Their preparation and characterization, Journal of Polymer Engineering, 38, pp. 1-8, (2018)
[4] FAIBUNCHAN P, PICHAIYUT S, CHUEANGCHAYAPHAN W, Et al., Influence type of natural rubber on properties of green biodegradable thermoplastic natural rubber based on poly (butylene succinate), Polymers for Advanced Technologies, 30, pp. 1010-1026, (2019)
[5] ZHOU Y, KOSUGI K, YAMAMOTO Y, Et al., Effect of non-rubber components on the mechanical properties of natural rubber, Polymers for Advanced Technologies, 28, pp. 159-165, (2016)
[6] LI C P, FENG C F, PENG Z, Et al., Ammonium-assisted green fabriacation of graphene/natural rubber latex composite, Polymer Composites, 34, pp. 88-95, (2013)
[7] SANTOS R J D, AGOSTINI D L D S, CABRERA F C, Et al., Sugarcane bagasse ash: new filler to natural rubber composite, Polímeros, 24, pp. 646-653, (2014)
[8] JIANG G F, LI X F, LIU F, Et al., Antibacterial properties of nano ZnO-graphene oxide and ZnO-graphene oxide/waterborne polyurethane composite coating, Acta Matriae Compositae Sinica, 35, 7, pp. 1930-1938, (2018)
[9] WANG D S, ZHANG Y Y, AN J, Et al., Preparation of Ag/low molecular weight chitosan composite colloids and their antibacterial activities, Acta Matriae Compositae Sinica, 31, 5, pp. 1250-1257, (2014)
[10] WANG J., Preparation and characterization of bacterial cellulose/curcumin composites, Acta Matriae Compositae Sinica, 35, 7, pp. 1897-1902, (2018)

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