MoO3 INTERFACE MODIFICATION IMPROVING PERFORMANCE OF BLADE COATED PEROVSKITE SOLAR CELLS

被引:0
|
作者
Guo X. [1 ]
Yao X. [1 ]
Liu Z. [1 ]
机构
[1] College of Optical and Electronic Technology, China Jiliang University, Hangzhou
来源
关键词
hole transport; interface modification; molybdenum oxide; perovskite solar cells; stability; thermal vapor deposition coating;
D O I
10.19912/j.0254-0096.tynxb.2023-1435
中图分类号
学科分类号
摘要
In this study,the influence of introducing MoO3 hole modification layer between hole transport layer Spiro-OMeTAD and Ag electrode on the photovoltaic performance of the blade- coated perovskite solar cell device was investigated. The mechanism was examined through a series of tests encompassing electrical conductivity measurement,steady-state photoluminescence spectra,contact angle with water,etc. The results of experiments and tests indicate that MoO3 can effectively improve hole transport capability and reduce interfacial resistance while protecting the underlying Spiro-OMeTAD and perovskite layers from water and oxygen degradation in the air. Based on MoO3 interface modification layers,the blade-coated perovskite solar cell device’s photovoltaic conversion efficiency increases from 15.14% to 18.30%,especially the average fill factor rises from 60% to 76%. At the same time,the stability of devices is also improved,with the unpackaged device still maintaining 90% of it initial efficiency after 400 hours. © 2024 Science Press. All rights reserved.
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页码:101 / 106
页数:5
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共 17 条
  • [1] HAO Y Z, LI J Q, QIAN J,, Et al., Blend of P3HT and Spiro-OMeTAD as photoactive layer and hole transport layer in hybrid solar cell[J], Acta energiae solaris sinica, 42, 12, pp. 459-464, (2021)
  • [2] GHOSH S,, Et al., Inorganic hole conducting layers for perovskite-based solar cells[J], The journal of physical chemistry letters, 5, 10, pp. 1748-1753, (2014)
  • [3] YE S Y, Et al., CuSCN-based inverted planar perovskite solar cell with an average PCE of 15.6% [J], Nano letters, 15, 6, pp. 3723-3728, (2015)
  • [4] MACDONALD T J., Lessons learned from Spiro- OMeTAD and PTAA in perovskite solar cells[J], Energy & environmental science, 14, 10, pp. 5161-5190, (2021)
  • [5] WANG S, HUANG Z H,, WANG X F,, Et al., Unveiling the role of tBP-LiTFSI complexes in perovskite solar cells[J], Journal of the American Chemical Society, 140, 48, pp. 16720-16730, (2018)
  • [6] KIM S G, LEE S H,, YANG I S, Et al., Effect of fluorine substitution in a hole dopant on the photovoltaic performance of perovskite solar cells[J], ACS energy letters, 7, 2, pp. 741-748, (2022)
  • [7] LUTHER J M,, Et al., Doping strategies for small molecule organic hole-transport materials: impacts on perovskite solar cell performance and stability[J], Chemical science, 10, 7, pp. 1904-1935, (2019)
  • [8] SARVARI H,, WANG X H,, WANG Y F,, Et al., Photovoltaic performance of lead- iodide perovskite solar cells fabricated under ambient air conditions with HTM solution excluding LiTFSI[J], IEEE journal of photovoltaics, 8, 4, pp. 1051-1057, (2018)
  • [9] BOYD C C,, CHEACHAROEN R, Et al., Understanding degradation mechanisms and improving stability of perovskite photovoltaics[J], Chemical reviews, 119, 5, pp. 3418-3451, (2019)
  • [10] DING C Z,, YIN L, ZHANG L P,, Et al., Revealing the mechanism behind the catastrophic failure of n- i- p type perovskite solar cells under operating conditions and how to suppress it [J], Advanced functional materials, 31, 40, (2021)