Catalytic application in lithium-sulfur batteries

被引:0
|
作者
Gao X. [1 ]
Deng Z. [1 ]
Li C. [1 ]
Wei Z. [1 ]
机构
[1] College of Chemistry and Chemical Engineering, Chongqing University, Chongqing
关键词
Catalysis; Electrochemistry; Lithium-sulfur battery; Reaction kinetics;
D O I
10.16085/j.issn.1000-6613.2021-1070
中图分类号
学科分类号
摘要
Due to its high energy density, environmental friendly, and low cost, lithium-sulfur battery (LiSB) has attracted more and more attentions as a promising next-generation energy storage device. However, the insulation property, polysulfide shuttle effect, and the slow redox kinetics of the active Li2Sx material could lead to serious capacity attenuation, and further affect the cycle stability of the batteries. Therefore, the use of catalytic materials to accelerate the redox kinetics and hence to increase the performance and stability of LiSB has extensively developed. In this review, the catalytic transformation of sulfur-related compounds were discussed from the aspects of polysulfides generation, sulfur species transformation, and of lithium sulfides deposition. The state-of-the-art researches of catalytic materials for LiSB was reviewed, including the design strategies, the catalytic mechanisms, and the corresponding evaluation methods, so as to provide new ideas for high activity LiSB catalyst materials. © 2021, Chemical Industry Press Co., Ltd. All right reserved.
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页码:5073 / 5087
页数:14
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  • [1] LIANG J, SUN Z H, LI F, Et al., Carbon materials for Li-S batteries: functional evolution and performance improvement, Energy Storage Materials, 2, pp. 76-106, (2016)
  • [2] LORGER S, USISKIN R E, MAIER J., Transport and charge carrier chemistry in lithium sulfide, Advanced Functional Materials, 29, 6, (2019)
  • [3] XU X B, RUAN J F, PANG Y P, Et al., Sulfur encapsulated in thermally reduced graphite oxide as a cathode for Li-S batteries, RSC Advances, 8, 10, pp. 5298-5305, (2018)
  • [4] YANG X X, LI X T, ZHAO C F, Et al., Promoted deposition of three-dimensional Li<sub>2</sub>S on catalytic Co phthalocyanine nanorods for stable high-loading lithium-sulfur batteries, ACS Applied Materials & Interfaces, 12, 29, pp. 32752-32763, (2020)
  • [5] FENG Y, WANG G, JU J G, Et al., Towards high energy density Li-S batteries with high sulfur loading: from key issues to advanced strategies, Energy Storage Materials, 32, pp. 320-355, (2020)
  • [6] KONG L, JIN Q, ZHANG X T, Et al., Towards full demonstration of high areal loading sulfur cathode in lithium-sulfur batteries, Journal of Energy Chemistry, 39, pp. 17-22, (2019)
  • [7] PAN H Y, TAN Z, ZHOU H H, Et al., Fe<sub>3</sub>C-N-doped carbon modified separator for high performance lithium-sulfur batteries, Journal of Energy Chemistry, 39, pp. 101-108, (2019)
  • [8] LIM W G, KIM S, JO C, Et al., A comprehensive review of materials with catalytic effects in Li-S batteries: enhanced redox kinetics, Angewandte Chemie International Edition, 58, 52, pp. 18746-18757, (2019)
  • [9] ZHAO Z X, YI Z L, LI H J, Et al., Synergetic effect of spatially separated dual co-catalyst for accelerating multiple conversion reaction in advanced lithium sulfur batteries, Nano Energy, 81, (2021)
  • [10] LIANG X, NAZAR L F., In situ reactive assembly of scalable core-shell sulfur-MnO<sub>2</sub> composite cathodes, ACS Nano, 10, 4, pp. 4192-4198, (2016)