Photoreactivity of C=N Double Bond Using N-(4-Pyridylmethylene)Aniline-Coordinated Zn(II) Complex Crystal

被引：0

作者：

Chen, Yun ^{[1
]}

Song, Yu ^{[1
]}

Saito, Yuki ^{[1
,2
]}

Zheng, Xin ^{[1
,2
]}

Pirillo, Jenny ^{[3
,4
]}

Hijikata, Yuh ^{[5
]}

Noro, Shin-ichiro ^{[1
,2
]}

机构：

[1] Hokkaido Univ, Grad Sch Environm Sci, Sapporo 0600810, Japan

[2] Hokkaido Univ, Fac Environm Earth Sci, Sapporo 0600810, Japan

[3] Nagoya Univ, Sch Engn, Grad Sch Engn, Dept Chem & Biotechnol, Furo Cho,Chikusa Ku, Nagoya 4648603, Japan

[4] Nagoya Univ, Grad Sch Engn, Dept Mat Chem, Furo-cho, Chikusa-ku, Nagoya 4648603, Japan

[5] Nagoya Univ, Inst Innovat Future Soc, Res Ctr Net Zero Carbon Soc, Furo Cho,Chikusa Ku, Nagoya 4648601, Japan

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2024年 / 27卷 / 32期

关键词：

Photochemistry; Zn(II) complex; <italic>trans</italic>-<italic>cis</italic> Isomerization; Photodimerization; -C=N- double bond; PHOTOCHEMICAL BEHAVIOR; 2-PHENYLBENZOXAZOLE; CYCLOADDITION; DIMERIZATION;

D O I：

10.1002/ejic.202400272

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The photoirradiation to the Zn complex crystal having N-(4-pyridylmethylene)aniline (4-pma) ligand with a central -C=N- bond led to no photodimerization reaction but only partial trans-cis isomerization of 4-pma. The reason why no photodimerization reaction occurred may be due to the stable twisted structure of 4-pma causing the prevention from proper approaching of neighboring 4-pma ligands.

引用

页数：5

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