Rapid Analysis of 90Sr and 55Fe in Spent Ion-exchange Resin of NPP

被引：0
|
作者：
Xu C. [1 ]
He W. [1 ]
Lei Q. [2 ]
Xu C. [1 ]
Liu Z. [1 ]
Jiang J. [1 ]
机构：
[1] Nuclear and Radiation Safety Center, Ministry of Ecology and Environment, Beijing
[2] Fujian Fuqing Nuclear Power Co., Ltd., Fuqing
来源：
Yuanzineng Kexue Jishu/Atomic Energy Science and Technology | 2021年 / 55卷 / 05期
关键词：
!sup]55[!/sup]Fe; !sup]90[!/sup]Sr; Extraction chromatography method; Liquid scintillation spectrometry; Spent ion-exchange resin;
D O I：
10.7538/yzk.2020.youxian.0404
中图分类号：
学科分类号：
摘要：
As a growing number of nuclear power units are putting into operation in China, a large amount of radioactive spent ion-exchange resin will be produced. The medium and long half-life radionuclides contained in spent ion-exchange resin are the focus of the safety assessment of disposal site, since they are critical to the long-term safety of disposal site. In this paper extraction chromatography and low background liquid scintillation spectrometry were adopted to establish a method for rapid analysis of 90Sr and 55Fe in the spent ion-exchange resins of NPP. The results show that the chemical recovery of Sr in this method is 94.94%, and the minimum detectable activity (MDA) is 5.51 Bq/kg, the chemical recovery of Fe using the two separation methods are 96.60% and 87.23%, and the MDA is 10.83 Bq/kg and 11.76 Bq/kg. © 2021, Editorial Board of Atomic Energy Science and Technology. All right reserved.
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页码：803 / 810
页数：7
相关论文
共 14 条
  • [1] (2008)
  • [2] ASTM D 5811-2000 Standard Test method for strontium-90 in water, (2008)
  • [3] TODOROVIC N, STOJKOVIC I, NIKOLOV J, Et al., <sup>90</sup>Sr determination in water samples using Cerenkov radiation, Journal of Environmental Radioactivity, 169-170, pp. 197-202, (2017)
  • [4] ASTM C 1507-2001 Standard test method for radiochemical determination of strontium-90 in soil, (2007)
  • [5] VAJDA N, GHODA-EAPHAHANI A, COOPER E, Et al., Determination of radiostrontium in soil samples using a crown ether, J Radioanal Nucl Chem, 162, 2, pp. 307-323, (1992)
  • [6] DULANSKA S, REMENEC B, BILOHUSTIN J, Et al., Rapid determination of <sup>90</sup>Sr in urine samples using AnaLig Sr-01[J], J Radioanal Nucl Chem, 295, pp. 2189-2192, (2013)
  • [7] HORWITZ E P, CHIARAZIA R, DIETZ M L., A novel strontium-seletive extraction chromatographic resin, Solv Extr Ion Exch, 10, pp. 313-336, (1992)
  • [8] XIE Xiangqian, YUAN Yanxia, Purification of radionuclide <sup>55</sup>Fe, Isotopes, 1, 2, pp. 38-40, (1988)
  • [9] WARWICK P E, CROUDACE I W., Isolation and quantification of <sup>55</sup>Fe and <sup>63</sup>Ni in reactor effluents using extraction chromatography and liquid scintillation analysis, Anal Chim Acta, 567, pp. 277-285, (2006)
  • [10] GUERIN N, DAI Xiongxin, Determination of <sup>55</sup>Fe in urine by liquid scintillation counting[J], Radioanal Nucl Chem, 304, pp. 1059-1069, (2015)
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