Preparation of modified hydroxyapatite/mixed acid-oxidized multi-walled carbon nanotubes and applications

被引:0
|
作者
He Y. [1 ,2 ,3 ]
Wang R. [1 ,2 ,3 ]
Zhou Y. [1 ,2 ,3 ]
Fan L. [1 ,2 ,3 ]
Dou Y. [1 ,2 ,3 ]
机构
[1] School of Water and Environment, Chang'an University, Xi'an
[2] Key Laboratory of Subsurface Hydrology and Ecological Effect in Arid Region, the Ministry of Education, Chang'an University, Xi'an
[3] Key Laboratory of Eco-hydrology and Water Security in Arid and Semi-arid Regions of Ministry of Water Resources, Chang'an University, Xi'an
关键词
adsorption performance; composite nanomaterials; hydroxyapatite; Mn(II)-containing wastewater; multi-walled carbon nanotubes;
D O I
10.13801/j.cnki.fhclxb.20230825.001
中图分类号
学科分类号
摘要
The development of nanocomposites with high dispersion and good adsorption properties is important for the removal of heavy metal ions from water bodies. Fluorine/carbon-doped hydroxyapatite (FCHAP) was prepared stepwise by microwave/light-wave combined heating assisted chemical precipitation using mixed-acid oxidized multi-walled carbon nanotubes (AO-MWCNTs) as the matrix and hydroxyapatite (HAP) was introduced and loaded onto AO-MWCNTs to synthesize FCH/AO-MWCNTs composites. The results show that the theoretical maximum adsorption capacity of FCH/AO-MWCNTs for Mn(II) is 317.5 mg/g, which is higher than that of AO-MWCNTs and each preparation intermediate. Combined with the characterization results of SEM-EDS, FTIR, XPS, Zeta, and BET, it is speculated that the new material FCH/AO-MWCNTs form more abundant pore structure and adsorption sites, and their dispersion and stability performance are excellent, and at the same time, the new material has broad application prospects in the removal of other heavy metals and recycling. © 2024 Beijing University of Aeronautics and Astronautics (BUAA). All rights reserved.
引用
收藏
页码:735 / 747
页数:12
相关论文
共 41 条
  • [1] QIN Deliang, CHEN Nanxiong, 2020 global manganese ore and the production brief in China's manganese products[J], China Manganese Industry, 39, 4, pp. 10-12, (2021)
  • [2] REN Hui, WU Hao, WANG Ziguo, Et al., Country's autonomousand controllable manganese industry supply chain building rely on domestic superhuge manganese ore, Coal Geology of China, 33, 11, pp. 1-3, (2021)
  • [3] ZHANG Qianrong, HE Zhaoqin, DENG Rong, The geological characteristics and economic significance on Yunnan Dounan Manganese Mine[J], World Nonferrous Metals, 15, pp. 120-121, (2017)
  • [4] CHENG Xiang, HU Peng, ZHANG Haikun, Et al., The main types, distribution and current development of manganese ore deposits[J], Geology in China, 48, 1, pp. 102-119, (2021)
  • [5] YU Q, LI S, LI H, Et al., Synthesis and characterization of Mn-slag based geopolymer for immobilization of Co[J], Journal of Cleaner Production, 234, pp. 97-104, (2019)
  • [6] ZHANG R, MA X, SHEN X, Et al., Life cycle assessment of electrolytic manganese metal production[J], Journal of Cleaner Production, 253, C, (2020)
  • [7] LYU Xiaoli, LIU Jingtao, ZHOU Bing, Et al., Fe and Mn distribution of groundwater in the Tacheng Basin, Xinjiang and its impact of human activities[J], Geology in China, 47, 6, pp. 1765-1775, (2020)
  • [8] SHEN Liangchen, HU Wenyong, ZHANG Lijuan, Et al., Characteristics and evaluation of heavy metal contamination in soil of typical waste dumping area, Nonferrous Metals Engineering, 12, 8, pp. 187-197, (2022)
  • [9] NKELE K, MPENYANA-MONYATSI L, MASINDI V., Challenges, advances and sustainabilities on the removal and recovery of manganese from wastewater: A review[J], Journal of Cleaner Production, 377, (2022)
  • [10] DEY S, TRIPATHY B, KUMAR M S, Et al., Ecotoxicological consequences of manganese mining pollutants and their biological remediation[J], Environmental Chemistry and Ecotoxicology, 5, pp. 55-61, (2023)