Synthesis and Characterization of Vinyl Terminated Urethane Resin Damping Materials

被引:0
|
作者
Sun Z. [1 ,2 ]
Li Y. [1 ]
Deng J. [1 ]
Rao Q. [1 ]
Mei Z. [2 ]
机构
[1] Department of Basics, Naval University of Engineering, Wuhan
[2] College of Naval Architecture and Ocean Engineering, Naval University of Engineering, Wuhan
关键词
Damping materials; Styrene; Vinyl terminated urethane resin;
D O I
10.16865/j.cnki.1000-7555.2021.0072
中图分类号
学科分类号
摘要
Polyurethane propylene glycol(PPG2000) and 2, 4-toluene diisocyanate (TDI) were used to synthesize a polyurethane prepolymer, which was capped with hydroxyethyl methacrylate (HEMA) to obtain a vinyl terminated urethane resin (VTUR). Styrene (St) as cross-linking monomer was added. Elastomers with different styrene contents were prepared with two curing agents, cumene hydrogen peroxide (CHP) and methyl ethyl ketone peroxide (MEKP). The synthesis of VTUR was analyzed, the influence of styrene content on the viscosity of the resins, and the influence of the amount of styrene and the type of curing agent on the damping and mechanical properties of the elastomers were also studied. The results show that VTUR was successfully synthesized and the addition of styrene decreases the viscosity of the resins; with the increase of styrene content, the damping peak of the elastomer gradually increases, and the peak temperature shifts to high temperature; the mechanical strength is increased. The elastomers made with CHP curing agent have better damping properties. © 2021, Editorial Board of Polymer Materials Science & Engineering. All right reserved.
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页码:54 / 60
页数:6
相关论文
共 15 条
  • [1] Xu K, Hu Q, Wu H, Et al., Designing a polymer-based hybrid with simultaneously improved mechanical and damping properties via a multilayer structure construction: structure evolution and a damping mechanism, Polymers, 12, (2020)
  • [2] Liu P Z, Li D F., Effect of AO-2246 on polyurethane damping and mechanical properties, Materials Development and Application, 34, 1, pp. 88-92, (2019)
  • [3] Wang X, Sun X P, Zhu J H., Study on the damping structure of PEA / TDI polyurethane copolymer damping structure, Materials Science and Technology, 26, 2, pp. 69-76, (2018)
  • [4] Liu Y S, Yan X, Li L., Structure and properties of hindered phenol-terminated polyurethane / epoxy blend damping materials, Polymer Materials Science & Engineering, 34, 1, pp. 79-82, (2018)
  • [5] Lee J M, Subramani S, Lee Y S., Thermal decomposition behavior of blocked diisocyanates derived from mixture of blocking agents, Macromolecular Research, 13, pp. 427-434, (2005)
  • [6] Beniah G, Liu K, Heath W H, Et al., Novel thermoplastic polyhydroxyurethane elastomers as effective damping materials over broad temperature ranges, European Polymer Journal, 84, pp. 770-783, (2016)
  • [7] Lv X H Z, Huang Z X, Shi M X, Et al., Composition distribution, damping and thermal properties of the thickness-continuous gradient epoxy/polyurethane interpenetrating polymer networks, Applied Sciences, 7, (2017)
  • [8] Yu W W, Zhang D Z, Du M, Et al., Role of graded length side chains up to 18 carbons in length on the damping behavior of polyurethane/epoxy interpenetrating polymer networks, European Polymer Journal, 49, pp. 1731-1741, (2013)
  • [9] Tang D Y, Zhang J S, Zhou D R, Et al., Influence of BaTiO<sub>3</sub> on damping and dielectric properties of filled polyurethane/unsaturated polyester resin interpenetrating polymer networks, Journal of Materials Science, 40, pp. 3339-3345, (2005)
  • [10] Talo M, Lanzara G, Krause B, Et al., Sliding Crystals" on low-dimensional carbonaceous nanofillers as distributed nanopistons for highly damping materials, ACS Applied Materials & Interfaces, 11, pp. 38147-38159, (2019)