Investigation on the inhibition effect and mechanism of hydrogen explosion by 2-bromo-3,3,3-trifluoropropene

This study investigated the effect of 2-bromo-3,3,3-trifluoropropene (2-BTP, C3H2BrF3) on hydrogen explosion behavior through a combination of experiments and simulations. The maximum explosion pressure (pmax), maximum pressure rise rate ((dp/dt)max), and critical inhibition concentration (CIC), across different equivalence ratios (Phi) and inhibitor concentrations (V), were obtained via experiments. The changes in adiabatic flame temperature, mole fraction of active radicals and sensitivity coefficient throughout the reaction were analyzed using CHEMKIN. The fuel-like properties of 2-BTP and the carbon monoxide (CO) produced by decomposition led to a promoting effect on the lean hydrogen explosion, primarily due to the elementary reactions R31, R806 and R882. When Phi >= 1.0, the capture of active radicals via elementary reactions such as R908, R1507, and R88 was enhanced, resulting in the dominance of inhibition and a corresponding inhibitory effect. Notably, 2-BTP exhibited an inhibitory effect for (dp/dt)max at any equivalence ratio. The CIC decreased from 10 % to 4 % when increasing equivalence ratios from 0.6 to 2.0. This work provides crucial data and a theoretical foundation for the prevention and control of hydrogen explosions.