The Adsorption Behavior and Reaction Mechanism of MnOx/TiO2 Catalytic Materials to NO and NH3 by DRIFTS

被引：0
|
作者：
Helian Y. [1 ]
Ma X. [1 ]
Cui S. [1 ]
Wan Y. [1 ]
机构：
[1] The Key Laboratory of New Functional Materials of Ministry of Education, College of Materials Science and Engineering, Beijing University of Technology, Beijing
来源：
| 2018年 / Cailiao Daobaoshe/ Materials Review卷 / 32期
关键词：
Acidolysis residue; Denitrification catalytic materials; Eley-Ridal mechanism; In situ diffuse reflectance infrared spectroscopy (DRIFTS); Selective catalytic reduction;
D O I：
10.11896/j.issn.1005-023X.2018.22.023
中图分类号：
学科分类号：
摘要：
MnOx/TiO2 catalysts has been shown excellent selective catalyst reduction (SCR) activity at low temperature.In order to understand its mechanism thoroughly and improve its catalytic activity further, in situ diffuse reflectance infrared spectroscopy (DRIFTS) was adopted to systematically analyze the single adsorption and coadsorption of NO and NH3 on MnOx/TiO2 catalytic materials. It is considered that the selective catalytic reduction process of the catalytic material conforms to the Eley-Ridal mechanism, and the reaction occurs between the adsorbed NH3 and the gaseous NO, while the adsorbed NO and the produced azotate and nitrite will occupy the active site of the catalytic material, which affects the adsorption of NH3 and leads to the decrease of the denitrification activity. © 2018, Materials Review Magazine. All right reserved.
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页码：3973 / 3978
页数：5
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