Experimental research on the surface tension of o-Xylene, m-Xylene and p-Xylene

被引:0
|
作者
Zhao K. [1 ]
Bi S. [1 ]
Wu J. [1 ]
机构
[1] Key Laboratory of Thermo-Fluid Science and Engineering of MOE, Xi'an Jiaotong University, Xi'an
来源
| 1600年 / Xi'an Jiaotong University卷 / 50期
关键词
Pendant drop method; Surface tension; Xylene isomers;
D O I
10.7652/xjtuxb201603008
中图分类号
学科分类号
摘要
The xylene isomers (o -xylene, m -xylene and p -xylene) have been widely used as the raw materials to synthesize of many organic compounds in petrochemical industry and the additives in the gasoline and alternative fuels. The pendant drop method experimental setup was developed and the pure heptane was measured to test the accuracy and the reliability of the setup. To obtain their surface tension and remedy the shortage of the existing data, the o -xylene, m -xylene and p -xylene were measured in the temperature range from 303.15 to 393.15 K and 57 groups of the experimental data were obtained in the present work. These experimental data were used to fit the equations of the surface tension. The absolute deviation between the calculated surface tension from the correlation equation and the experiment results is within ±0.1 mN·m-1. The experimental data and calculated equations obtained in this paper can provide the basic thermal physical data for the engineering application of o -xylene, m -xylene and p -xylene. © 2016, Xi'an Jiaotong University. All right reserved.
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页码:50 / 54and100
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  • [1] Rodrigues W.L., Mattedi S., Abreu J.C.N., Vapor-liquid equilibria data for binary systems of ethylbenzene plus xylene isomers at 100.65 kPa, Journal of Chemical and Engineering Data, 50, 4, pp. 1134-1138, (2005)
  • [2] Battin-Leclerc F., Bounaceur R., Belmekki N., Et al., Experimental and modeling study of the oxidation of xylenes, International Journal of Chemical Kinetics, 38, 4, pp. 284-302, (2006)
  • [3] Shen H.-P.S., Oehlschlaeger M.A., The autoignition of C<sub>8</sub>H<sub>10</sub> aromatics at moderate temperatures and elevated pressures, Combustion and Flame, 156, 5, pp. 1053-1062, (2009)
  • [4] Donaldson R.E., Quayle O.R., A study of organic parachors. X. parachors of American petroleum institute-national bureau of standards hydrocarbons: Benzene and homologs of benzene, Journal of the American Chemical Society, 72, 1, pp. 35-36, (1950)
  • [5] Ouyang G.F., Yang Y.Y., Lu S.S., Et al., Excess molar volumes and surface tensions of xylene with acetone or 2-butanone at 298.15 K, Journal of Chemical and Engineering Data, 49, 2, pp. 330-332, (2004)
  • [6] Chen Z.Q., Ma P.S., Xia S.Q., Et al., Surface tension of o -xylene plus acetic acid and m -xylene plus acetic acid binary mixtures from 303.15 K to 343.15 K, Journal of Chemical and Engineering Data, 52, 2, pp. 454-457, (2007)
  • [7] Deng J.H., Tan H.F., Yang Y.Y., Et al., Densities and surface tensions of propyl acetate plus xylenes or plus ethylbenzene from(298.15 to 308.15) K, Journal of Chemical and Engineering Data, 52, 3, pp. 1131-1135, (2007)
  • [8] Yang Y.Y., Zhu Y.M., Peng J.L., Et al., Excess thermodynamic functions derived from densities and surface tensions of (p -or o -xylene plus ethylene glycol dimethyl ether) between the temperatures (298.15 and 308.15) K, Journal of Chemical Thermodynamics, 41, 9, pp. 1000-1006, (2009)
  • [9] Kumar M.P., Tasleem S., Rakesh Kumar G., Surface tension of binary mixtures of o -xylene (1)+isopropanol (2) and o -xylene (1)+n -butanol (2) from 303.15 to 343.15 K, Journal of the Institution of Engineers: Series E Chemical and Textile Engineering, 94, 1, pp. 47-53, (2013)
  • [10] Richards T.W., Speyers C.L., Carver E.K., The determination of surface tension with very small volumes of liquid, and the surface tensions of octanes and xylenes at several temperatures, Journal of the American Chemical Society, 46, 5, pp. 1196-1207, (1924)