Nearly real trajectories in complex semiclassical dynamics

被引:0
|
作者
Van Voorhis, Troy [1 ]
Heller, Eric J. [1 ]
机构
[1] Dept. of Chem. and Chemical Biology, Department of Physics, Harvard University, Cambridge, MA 02138, United States
关键词
Autocorrelation function - Photodissociation spectrum - Quantum dynamics - Quantum propagator - Quartic anharmonic oscillator - Semiclassical propagator;
D O I
暂无
中图分类号
学科分类号
摘要
The possibility that the dominant contributions by themselves may give a faithful representation of the true result was examined. As such, calculations of the auto-correlation function of the quartic anharmonic oscillator and the photodissociation of CO2, which show that including only the nearly real trajectories can give excellent results for realistic potentials were given. The use of only nearly real paths was particularly appealing because it allows one to overcome both of the major obstacles that have heretofore limited complex semiclassical approaches.
引用
收藏
页码:1 / 050501
相关论文
共 50 条
  • [1] Nearly real trajectories in complex semiclassical dynamics
    Van Voorhis, T
    Heller, EJ
    [J]. PHYSICAL REVIEW A, 2002, 66 (05): : 4
  • [2] Semiclassical propagation of wavepackets with complex and real trajectories
    de Aguiar, MAM
    Baranger, M
    Jaubert, L
    Parisio, F
    Ribeiro, AD
    [J]. JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 2005, 38 (21): : 4645 - 4664
  • [3] Semiclassical propagation of coherent states using complex and real trajectories
    Novaes, M
    de Aguiar, MAM
    [J]. PHYSICAL REVIEW A, 2005, 72 (03):
  • [4] SEMICLASSICAL APPROXIMATION WITH COMPLEX TRAJECTORIES
    KNOLL, J
    SCHAEFFER, R
    [J]. PHYSICS LETTERS B, 1974, B 52 (02) : 131 - 134
  • [5] Semiclassical tunnelling of wavepackets with real trajectories
    Jaubert, L. D. C.
    de Aguiar, M. A. M.
    [J]. PHYSICA SCRIPTA, 2007, 75 (03) : 363 - 373
  • [6] Semiclassical approximations based on complex trajectories
    Ribeiro, AD
    de Aguiar, MAM
    Baranger, M
    [J]. PHYSICAL REVIEW E, 2004, 69 (06):
  • [7] Semiclassical nonadiabatic dynamics with quantum trajectories
    Rassolov, VA
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U2843 - U2843
  • [8] Semiclassical dynamics based on quantum trajectories
    Garashchuk, S
    Rassolov, VA
    [J]. CHEMICAL PHYSICS LETTERS, 2002, 364 (5-6) : 562 - 567
  • [9] Semiclassical nonadiabatic dynamics with quantum trajectories
    Rassolov, VA
    Garashchuk, S
    [J]. PHYSICAL REVIEW A, 2005, 71 (03)
  • [10] Real trajectories in the semiclassical coherent state propagator
    Novaes, M
    [J]. JOURNAL OF MATHEMATICAL PHYSICS, 2005, 46 (10)