Design and preparation of ferulic acid surface-imprinted material and its molecular recognition characteristic

被引:0
|
作者
Yang Q. [1 ]
Xu R. [1 ]
Men J. [1 ]
Gao B. [1 ]
机构
[1] Department of Chemical Engineering, North University of China, Taiyuan
来源
Gao, Baojiao (gaobaojiao@126.com) | 1600年 / Sichuan University卷 / 32期
关键词
Ferulic acid; Molecule surface-imprinting; Silica gel particles; Surface-initiated graft-polymerization;
D O I
10.16865/j.cnki.1000-7555.2016.02.032
中图分类号
学科分类号
摘要
Ferulic acid (FA) is a phenolic acid with styrene-type that widely exists in plant tissues, and possesses many important bioactivities and pharmacological activities. For the polymerizable double bond that is contained in the molecular structure of FA, the molecule imprinting of FA, MIP-QP/SiO2 was effectively realized by the new surface imprinting technology of "pre-graft polymerizing and post-imprinting". The experimental results show that the imprinted particles MIP-QP/SiO2 have the excellent binding affinity and specific recognition selectivity. The binding capacity gets up to 182 mg/g. Relative to a depside, chlorogenic acid, of which the molecular structure is similar to that of FA to a certain degree, the coefficient of selectivity of MIP-QP/SiO2 particles reaches up to 7.15, while relative to another phenolic acid, caffeic acid, of which the molecular structure is very similar to that of FA, the coefficient of selectivity of MIP-QP/SiO2 particles reaches 3.27. © 2016, Editorial Board of Polymer Materials Science & Engineering. All right reserved.
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页码:173 / 178and185
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