Effect of inhibiting montmorillonite hydration swelling on coal slurry filtration

被引:0
|
作者
Liu G. [1 ]
Liu W. [1 ]
Wang D. [1 ,2 ]
Yang Z. [1 ]
机构
[1] School of Chemical and Environmental Engineering, China University of Mining and Technology(Beijing), Beijing
[2] China Merchants Ecological Environmental Protection Technology Co., Ltd., Chongqing
关键词
Coal slurry; Filtration; Hydration swelling; Inhibitor; Montmorillonite;
D O I
10.13225/j.cnki.jccs.2018.0068
中图分类号
学科分类号
摘要
In order to investigate the effect of inhibiting montmorillonite hydration swelling on coal slurry filtra-tion, the filtration of coal slurry containing montmorillonite was carried out under inhibitory and non-inhibitory state, and the potassium chloride and three methyl benzyl ammonium chloride(TMBAC) were used as inhibitors. The results show that the hydration swelling of montmorillonite can be inhibited by potassium chloride and TMBAC. When the mass fraction of potassium chloride is 1.12% and the mass fraction of TMBAC is 0.4%, the anti-swelling rate of montmorillonite can reach 90%.The filtration of coal slurry containing montmorillonite carried out under inhibitory has lower filter cake moisture, shorter filtration time and larger dehydration rate, furthermore, the effect of filtration for coal slurry containing montmorillonite is better when using TMBAC as inhibitor. The hydration energies of K+ and C6H5CH2-N+(CH3)3 is lower. Therefore, K+ and C6H5CH2-N+(CH3)3 can adsorb on the interlayer of montmorillonite and limit the self-diffusion of interlayer hydrone and sodion. Besides, C6H5CH2-N+(CH3)3 can act as a filter aid and adsorb on the surface of montmorillonite and coal particles, which will increase the hydrophobicity of montmorillonite and coal particles. © 2018, Editorial Office of Journal of China Coal Society. All right reserved.
引用
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页码:553 / 559
页数:6
相关论文
共 21 条
  • [1] Wang W., Li Z., Yan L., Et al., Separating chara- cteristics of coal and water with microwave irradiation preprocessing, Journal of China Coal Society, 39, pp. 503-507, (2014)
  • [2] Meng Z., Peng S., Qu H., The relationship between composition and texture of sedimentary rock and its mechanical properties in the roof and floor, Chinese Journal of Rock Mechanics and Engineering, 19, 2, pp. 136-139, (2000)
  • [3] Liu Q., Xu H., Zhang P., Crystallinity difference for various origin of kaolinites in coal measures, Journal of China Coal Society, 25, 6, pp. 576-580, (2000)
  • [4] Xu D., Wu H., Zhu Z., Et al., Mechanism of hetero-aggregation of montmorillonite and coal, Journal of China Coal Society, 42, 5, pp. 1284-1289, (2017)
  • [5] Lin Z., Yang C., Shen Z., Et al., The properties and sedimentation characteristics of extremelysliming coal slime water, Journal of China Coal Society, 35, 2, pp. 312-315, (2010)
  • [6] Feng L., Liu J., Zhang M., Et al., Analysis on influencing factors of sedimentation characteristics of coal slime water, Journal of China University of Mining & Technology, 5, pp. 671-675, (2010)
  • [7] Zhang Z., Li Y., Tong Z., Et al., Adsorption characteristics of metal ions on kaolinite, Journal of Mining Science and Technology, 2, 3, pp. 294-300, (2017)
  • [8] Zhang Z., Liu J., Feng L., Et al., Calculation of critical hardness of coal slime water system based on DLVO theory, Journal of China University of Mining & Technology, 43, 1, pp. 120-125, (2014)
  • [9] Wang J., Structure and interlayer expansion of clay minerals, Journal of Anqing Teachers College(Natural Science Edition), 1, 4, pp. 14-16, (1995)
  • [10] Xu Z., Liu J., Wang H., Et al., Inhibition of potassium ions on hydration swelling of montmorillonite, Journal of China Coal Society, 41, 2, pp. 464-468, (2016)