Preparation and performance of graphene oxide doped reverse osmosis mixed matrix membrane

被引:0
|
作者
Chen X. [1 ]
Fu B. [2 ]
Zhong M. [2 ]
Xu L. [2 ]
Zhou Y. [1 ]
Gao C. [1 ]
机构
[1] Ocean College, Zhejiang University of Technology, Hangzhou, 310014, Zhejiang
[2] College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014, Zhejiang
来源
Huagong Xuebao/CIESC Journal | 2018年 / 69卷 / 01期
关键词
Graphene oxide; Membrane; Reverse osmosis; Secondary interface polymerization; Separation;
D O I
10.11949/j.issn.0438-1157.20170977
中图分类号
学科分类号
摘要
The aromatic polyamide reverse osmosis membrane is poor in anti-fouling performance and chlorine resistance, which is limiting its application in some fields. The commercial reverse osmosis membrane was modified by the secondary interface polymerization method of adding graphene oxide (GO) to the oil phase. The separation performance and chlorine resistance of GO-doped reverse osmosis mixed matrix membranes were evaluated. The properties of the membranes were characterized by water contact angle, Zeta potential,scanning electron microscopy (SEM) and atomic force microscopy(AFM). The results show that the addition of GO increases the hydrophilicity, separation performance and chlorine resistance of the membrane. With 30 mg•L-1GO content, the flux and rejection rate of the membrane reach peak values of (77.7±0.9) L•m-2 •h-1 and 97.6%±0.5%, increasing 38.4% and 4.5% respectively. When the chlorination intensity is less than 4800 mg•L-1•h, the changes of water flux and salt rejection rate of the membrane are not obvious. © All Right Reserved.
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页码:429 / 434
页数:5
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  • [1] Shannon M.A., Bohn P.W., Elimelech M., Et al., Science and technology for water purification in the coming decades, Nature, 452, 7185, pp. 301-310, (2008)
  • [2] Lalia B.S., Kochkodan V., Hashaikeh R., Et al., A review on membrane fabrication: structure, properties and performance relationship, Desalination, 326, 10, pp. 77-95, (2013)
  • [3] Zhao G.H., Tong Z.D., Desalination Engineering and Technology, (2012)
  • [4] Xu G.R., Wang S.H., Zhao H.L., Et al., The development trend and expectation of the polyamide-based reverse osmosis desalination membranes, Membrane Science and Technology, 35, 5, pp. 122-126, (2015)
  • [5] Lee K.P., Arnot T.C., Mattia D., A review of reverse osmosis membrane materials for desalination-development to date and future potential, Journal of Membrane Science, 370, 1, pp. 1-22, (2011)
  • [6] Gao C.J., Zhou Y., Liu L.F., Recent development and prospect of seawater reverse osmosis desalination technology, Journal of Ocean Technology, 35, 1, pp. 1-14, (2016)
  • [7] Li D., Wang H., Recent developments in reverse osmosis desalination membranes, Journal of Materials Chemistry, 20, 22, pp. 4551-4566, (2010)
  • [8] Zhang Y.S., Wei Y.Y., Cao Z., Et al., Progress and prospect in the development of reverse osmosis membrane technology, Chemical Industry and Engineering, 32, 5, pp. 8-19, (2015)
  • [9] Shenvi S.S., Isloor A.M., Ismail A.F., A review on RO membrane technology: developments and challenges, Desalination, 368, pp. 10-26, (2015)
  • [10] Greenlee L.F., Lawler D.F., Freeman B.D., Et al., Reverse osmosis desalination: water sources, technology, and today's challenges, Water Research, 43, 9, pp. 2317-2348, (2009)