Synthesis and properties of new optically active poly(ether imides) based on aromatic diols and N,N'-[4,4'-carbonyl-bis(phthaloylimido)]-bis(L-leucine) dichloroanhydride

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Mallakpour, Sh.E.
Hajipour, A.-R.
Zamanlou, M.-R.
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Alcohols - Amines - Carboxylic acids - Optical rotation - Polycondensation;
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New optically active poly(ether imides) with a reduced viscosity of 0.14-0.34 dl/g were synthesized by the low-temperature polycondensation of aromatic diols with N,N'-[4,4'-carbonyl-bis(phthaloylimido)]-bis(L-leucine) dichloroanhydride in CHCl3 in the presence of triethylamine. Temperatures corresponding to the 5% weight loss of the produced polymers upon heating under nitrogen at a rate of 10 K/min fall in the 314-361°C range.
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页码:407 / 411
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