Research on carbon fiber composite properties based on (polyether sulfone)/ cyanate ester semi-interpenetrating resin system

被引:0
|
作者
Xu P. [1 ,2 ]
Wu F. [1 ]
Zhu Z. [1 ]
Hou J. [1 ]
机构
[1] School of Materials Science and Engineering, Chang'an University, Xi'an
[2] Engineering Research Center for Transportation Paving Materials, Ministry of Education, Chang'an University, Xi'an
关键词
Carbon fiber composites; Cyanate ester resin; Mechanical properties; Polyether sulfone; Thermal expansion properties;
D O I
10.13801/j.cnki.fhclxb.20210819.003
中图分类号
学科分类号
摘要
Cyanate ester (CE) resin, which has high glass transition temperature, low curing shrinkage and excellent dielectric properties, is commonly used as the material of high temperature resistant or microwave absorption in the aerospace field. However, after high temperature curing, the poor immigration adhesion between CE resin and carbon fiber (CF) would result in brittleness of its composite product. In addition, the preparation process of composites is complex, resulting in delamination damage. Therefore, the product quality and practical application are considerably affected. In this paper, polyether sulfone (PES) was used to modify CE resin and prepare prepreg. It prepares prepreg with good wettability and can apply to various dry forming composite preparation processes. The results show that the introduction of PES can significantly enhance the mechanical properties and thermal stability of CF/CE resin matrix composites. Compared with the CF/CE unidirectional plate, the flexural strength of 7.5wt%PES-CF/CE unidirectional plate is increased by 17%; the interlaminar shear strength is increased by 31%; the impact strength is increased by 39%; and the longitudinal thermal expansion coefficient is reduced from −2.07×10−8 K−1 to −10.7×10−8 K−1; the transverse thermal expansion coefficient is reduced by 20%. The modification effect is signifi-cant. Copyright ©2022 Acta Materiae Compositae Sinica. All rights reserved.
引用
收藏
页码:2639 / 2648
页数:9
相关论文
共 32 条
  • [1] ZHANG Xuan, SHEN Zhen, Advances in manufacturing technology of advanced composite materials in the field of aerospace, Textile Herald, pp. 72-79, (2018)
  • [2] CHEN Xiangbao, ZHANG Baoyan, XING Liying, The development and application status of advanced resin matrix composite materials, Progress in Chinese Materials, 28, 6, pp. 2-12, (2009)
  • [3] HAO Jianwei, The technical status and development direction of advanced resin-based composite materials, Aeronautical Manufacturing Technology, 3, pp. 22-25, (2001)
  • [4] DU Shanyi, Advanced composite materials and aerospace, Journal of Composite Materials, 24, 1, pp. 1-12, (2007)
  • [5] HE Dongxiao, Overview of the application of advanced composite materials in aerospace, High-Tech Fiber & Application, 2, pp. 9-11, (2006)
  • [6] MA Junxian, LEI Xuefeng, SANG Xiaohui, Et al., Preparation and properties of cyanate ester/amino-terminated polyether resin, Thermosetting Resins, 3, 6, pp. 1-26, (2018)
  • [7] LIU Feng, ZHOU Heng, ZHAO Tong, The latest research progress of high-performance resin matrix, Aerospace Materials Technology, 42, 4, pp. 1-6, (2012)
  • [8] HU J T, GU A, LIANG G, Et al., Preparation and properties of maleimide functionalized hyperbranched polysiloxane and its hybrids based on cyanate ester resin, Journal of Applied Polymer Science, 126, 1, pp. 205-215, (2012)
  • [9] ZENG Pingzhang, PEI Jianzhong, FANG Changqing, Et al., Modification of cyanate ester resin by epoxy-functionalized polyhedral oligomeric silsesquioxane, Advanced Materials Research, 549, pp. 314-317, (2012)
  • [10] FENG, CHEN, LI, Et al., Low-temperature cure high-performance cyanate ester resins/microencapsulated catalyst systems, Polymer Engineering & Science, 53, 9, pp. 1871-1877, (2013)