Effect of epoxy curing system on intumescent flame retardant coatings

被引:0
|
作者
Wang K. [1 ]
Li D. [1 ]
Yang R. [1 ]
机构
[1] National Engineering Research Center of Flame Retardant Material, School of Material Science and Engineering, Beijing Institute of Technology, Beijing
来源
Li, Dinghua (dli@bit.edu.cn) | 1600年 / Sichuan University卷 / 32期
关键词
Charring; Epoxy emulsion; Fire resistance; Flame retardant coating;
D O I
10.16865/j.cnki.1000-7555.2016.07.010
中图分类号
学科分类号
摘要
Two kinds of intumescent flame retardant coatings were prepared individually with two kinds of epoxy curing system as binders, when ammonium polyphosphate(APP), dipentaerythritol(DPER) and melamine(MEL) were used as intumescent flame retardants. The fire-proofing and combustion performances of two coatings and mechanical strength of residue char were investigated by back temperature tester, cone calorimeter, thermogravimetric analyzer and stress rheometer. The data show that aromatic curing agent can improve flame retardancy more efficiently than aliphatic curing agent. The epoxy coatings with aromatic curing agent contribute a lot to the charring and result in more compact and stronger char. Therefore, the heat and smoke release are reduced during combustion, and the fire resistant performances are also enhanced significantly. © 2016, Editorial Board of Polymer Materials Science & Engineering. All right reserved.
引用
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页码:51 / 56
页数:5
相关论文
共 12 条
  • [1] Bras M.L., Bourbigot S., Comprehensive study of the degradation of all intumescent EVA-based material during combustion, J. Mater. Sci., 34, pp. 5777-5782, (1999)
  • [2] Gardner L., Baddoo N.R., Fire testing and design of stainless steel structures, J. Steel Res., 62, pp. 532-543, (2006)
  • [3] Wang G.J., Yang J.Y., Influences of binder on fire protection and anticorrosion properties of intumescent fire resistive coating for steel structure, Surf. Coat. Technol., 204, pp. 1186-1192, (2010)
  • [4] Gardelle B., Duquesne S., Rerat V., Et al., Thermal degradation and fire performance of intumescent silicone-based coatings, Polym. Adv. Technol., 24, pp. 62-69, (2013)
  • [5] Gardelle B., Duquesne S., Bourbigot S., Et al., Resistance to fire of silicone-based coatings: fire protection of steel against cellulosic fire, J. Fire Sci., 32, pp. 374-387, (2014)
  • [6] Barletta M., Lusvarghi L., Pighetti F., Et al., Epoxy-based thermosetting powder coatings: surface appearance, scratch adhesion and wear resistance, Surf. Coat. Technol., 201, pp. 7479-7504, (2007)
  • [7] Shi P., Li F.Z., Zhang C., Improvement of fire-proof performance of intumescent vinylacetate-acrylic coatings modified with epoxy emulsion, Paint & Coatings Industry, 41, 9, pp. 34-37, (2011)
  • [8] Wang G.J., Yang S., Influence of curing agents on epoxy emulsion-based intumescent fire retardant coatings, Paint & Coatings Industry, 39, 4, pp. 41-44, (2009)
  • [9] Yin J.J., Sun J.C., Study of waterborne polyurethane flame retardant coating modified by epoxy resin, Electroplating&Finishing, 28, 5, pp. 56-58, (2009)
  • [10] Wang G.J., Yang J.Y., Influences of molecular weight of epoxy binder on fire protection of waterborne intumescent fire resistive coating, Surf. Coat. Technol., 206, pp. 2146-2151, (2012)