Synthesis and crystal structure of inorganic-organic hybrid crystal [C12H11N2O2] [Cd(SCN)3]

被引：0

作者：

Dang, Dong-Bin ^{[1
]}

Sun, Ji-De ^{[1
]}

Bai, Yan ^{[1
]}

Shang, Wei-Li ^{[1
]}

Gao, Hui ^{[1
]}

机构：

[1] Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China

来源：

Rengong Jingti Xuebao/Journal of Synthetic Crystals | 2009年 / 38卷 / 03期

关键词：

X ray diffraction - Hybrid materials - Cadmium compounds - Ions - Single crystals;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A new inorganic-organic hybrid compound [NO2BzPy] [Cd(SCN)3], where [NO2BzPy]+=1-(4′-nitro-benzyl)pyridinium, was synthesized and characterized by elemental analysis, IR spectroscopy, TG analysis and single-crystal X-ray diffraction. The results of IR analysis show that the SCN-anions are coordinated in a di-1, 3-μ bridge mode. Adjacent Cd(II) atoms are linked by three 1, 3-μ-SCN-anions forming infinite [Cd(SCN)3-]∞zigzag polymeric chains. In the crystal structure of the title compound, cations and ations form completely segregated stacking column along the direction of c-axis. Crystal data: monoclinic, space group P2(1)/c with a=1.1260(3) nm, b=1.5080(4) nm, c=1.1070(3) nm, β=105.410(10)°, V=1.8121(8) nm3, Z=4, dc=1.840 g·cm3, T=293(2) K, μ=1.571 mm-1, F(000)=992, R1=0.0343, wR2=0.0750 [I>2σ (I)]. Thermogravimentric analysis reveal the organic molecule is lost in the range of 180-305°C and three SCN-anions are lost after 305°C accompanying the sublimation of cadmium.

引用

页码：608 / 611

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