Solute Transport in a Multi-Channel Karst System with Immobile Zones: An Example of Downtown Salado Spring Complex, Salado, Texas

To investigate the influence of flow rate increment on the solute transport parameter of immobile zones in a karst system, a dye tracer test was conducted in the Downtown Salado Spring Complex (DSSC) comprising three springs: Big Boiling, Anderson, and Doc Benedict springs. The Multiflow two-region nonequilibrium model (2RNE) was used to simulate the breakthrough curve (BTC) of the springs, and changes in the solute transport parameters in response to flow rate increment were observed. The simulation result showed that the 2RNE model was capable of reproducing the BTC of all the DSSC springs, with an R-squared value greater than 0.9 in all flow rate increment scenarios. The research demonstrates that a positive correlation will exist between the flow rate and solute transport parameter of the immobile zones if the tracer transport to the spring is truly influenced by immobile zones. In contrast, a negative correlation will exist between the flow rate and mass transfer coefficient if the immobile zone has less influence. Overall, the research provides insights into contaminant movement in karst by documenting how tracers are retained in the immobile fluid zone.