Synthesis and Charaterization of 3，5，7-Triamino［1，2，4］triazolo［4，3-a］［1，3，5］triazine Pentazolate Salt

被引：0

作者：

Jiang S.-J. ^{[1
]}

Qin Y.-Q. ^{[1
]}

Xu Y.-G. ^{[1
]}

Lu M. ^{[1
]}

Wang P.-C. ^{[1
]}

机构：

[1] School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing

来源：

Hanneng Cailiao/Chinese Journal of Energetic Materials | 2024年 / 32卷 / 06期

基金：

中国国家自然科学基金;

关键词：

energetic ion salt; nitrogen-rich polycyclic compound; pentazole; performance; synthesis;

D O I：

10.11943/CJEM2024028

中图分类号：

学科分类号：

摘要：

A novel nonmetallic salt，3，5，7-triamino［1，2，4］triazolo［4，3-a］［1，3，5］triazine pentazolate（4），was synthesized through a metathesis reaction by employing AgN5 as precusor with 3，5，7-triamino［1，2，4］triazolo［4，3-a］［1，3，5］triazine hydrochloride. The structural characterization were carried out by X-ray single crystal diffraction，infrared spectroscopy（IR），elemental analysis（EA），nuclear magnetic resonance（NMR），and thermal decomposition behavior were determined by thermogravi-metric analysis（TG）and differential scanning calorimetry（DSC）. The enthalpy of formation of compound 4 was calculated using atomization method，the detonation performance was predicted using EXPLO5，and sensitivity was tested using BAM testing method. The results show that compound 4 exhibits a monoclinic crystal structure with a crystal density of 1.644 g·cm-3 and belongs to the P21/n space group. This compound has a nitrogen content of 77%，a thermal decomposition temperature of 113.8 ℃ ，and an enthalpy of formation of 491.5 kJ·mol-1. Furthermore，its detonation velocity was calculated at 7913 m·s-1，detonation pressure at 19.6 GPa；The impact sensitivities measured were >40 J，and friction sensitivity >360 N. © 2024 Institute of Chemical Materials, China Academy of Engineering Physics. All rights reserved.

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页码：601 / 607

页数：6

共 24 条

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