Upconversion Luminescence of Sm2+ Ions Based on Cooperative Energy Transfer

被引:0
|
作者
Liu X.-H. [1 ]
Ma S.-T. [1 ]
Zheng K.-Z. [1 ]
Qin W.-P. [1 ]
机构
[1] College of Electronic Science & Engineering, Jilin University, Changchun
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关键词
Cooperative energy transfer; Sm[!sup]2+[!/sup; Upconversion luminescence; Yb[!sup]3+[!/sup]-dimer;
D O I
10.3788/fgxb20173811.1413
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学科分类号
摘要
We report the observation of upconversion luminescence from Sm2+ ions, which demonstrate that changeable valence lanthanides can served as the ions for optical frequency transformation. Upon the excitation of 980 nm diode laser, the doped Sm2+ ions in the hybrid material of BaFCl0.5Br0.5:1%Sm2+-CaF2:1%Yb3+ emit red upconversion fluorescence peaked at 631, 644, 665, 689, 704, 729 nm from the 5D0,1→7F0,1,2 transitions, respectively. By transient dynamic analysis, we attribute the excitation of Sm2+ ions to the cooperation energy transfer process: two excited Yb3+ ions simultaneously transfer their energy to one Sm2+ ion. © 2017, Science Press. All right reserved.
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页码:1413 / 1419
页数:6
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