Mn and Mo co-doped NiS nanosheets induce abundant Ni3+-O bonds for efficient electro-oxidation of biomass

被引：0

作者：

Ren, Pengfei ^{[1
]}

Wang, Zixuan ^{[1
]}

Zhang, Wenchao ^{[2
]}

Duan, Fang ^{[1
]}

Lu, Shuanglong ^{[1
]}

Du, Mingliang ^{[1
]}

Zhu, Han ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Synthet & Biol Colloids, Wuxi 214122, Jiangsu, Peoples R China

[2] Suzhou Univ Sci & Technol, Sch Chem & Life Sci, Suzhou 215009, Jiangsu, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 91期

基金：

中国国家自然科学基金;

关键词：

Electrolysis;

D O I：

10.1039/d4cc04818k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MnMo-NiS were synthesized for electro-oxidizing ethylene glycol (EG), glycerol (GLY), and 5-hydroxymethylfurfural (HMF), achieving faradaic efficiencies of 97.5%, 98.6%, and 99.2%, and yield rates of 615.7, 475.5, and 333.9 mu mol h-1 cm-2. In situ Raman spectroscopy and multi-step chronoamperometry reveal that Ni3+-O is the active site.

引用

页码：13392 / 13395

页数：4

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