One-step synthesis of silver nanoparticles embedded with polyethylene glycol as thin films

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[1] Fahmy, Alaa
[2] El-Zomrawy, Adham
[3] Saeed, Ahmed M.
[4] Sayed, Ahmed Z.
[5] El-Arab, Mohamed Alaa Ezz
[6] Shehata, Hassan A.
[7] Friedrich, Jörg
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Friedrich, Jörg (friedrich-erkner@t-online.de) | 1600年 / Taylor and Francis Ltd.卷 / 31期
关键词
Deposition - High resolution transmission electron microscopy - X ray photoelectron spectroscopy - Heating - Polyethylenes - Synthesis (chemical) - Colloids - Electrospray ionization - Metal nanoparticles - Polyethylene glycols - Silicon wafers - Surface treatment - Fourier transform infrared spectroscopy - Silver nanoparticles - Medical applications - Nanocomposite films;
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摘要
Silver nanoparticles (Ag NPs) embedded and stabilized with polyethylene glycol (PEG) were synthesized as colloids by heating and exposure to sunlight (direct and indirect) irradiation as green method. The deposition of Ag NP-PEGs onto Si-wafers was also made using the electrospray ionization deposition technique. The generating of Ag NP-PEGs as colloids was examined by UV–visible spectroscopy (UV–Vis) and transmission electron microscopy (TEM). The chemical composition of the resulted nanocomposites was evaluated by Fourier transform infrared (FTIR) and that of thin-film surfaces by X-ray photoelectron spectroscopy. Structure–property relationships of Ag-PEG nanocomposites prepared by heating were discussed in dependence on the time of heating. The UV–visible results confirmed the successful synthesis of spherical Ag NPs with absorption peaks at a wavelength of λ = 413 nm for the heating method and at λ = 418 as well as 449 nm for direct and indirect exposure to the sunlight. Ag-PEG nanocomposite thin films showed excellent antimicrobial activity. These results revealed that the Ag-PEG nanocomposites thin films can be used as potential materials in biomedical applications. © 2016 Informa UK Limited, trading as Taylor & Francis Group.
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