Structural, magnetic and magnetocaloric properties of (Mn, Co)2(Si, P) compounds

被引：0
|
作者：
Ma, Lei [1 ,2 ]
Guillou, F. [1 ]
Yibole, H. [1 ]
Miao, X.F. [1 ]
Lefering, A.J.E. [1 ]
Rao, G.H. [2 ]
Gu, Z.F. [2 ]
Cheng, G. [2 ]
Brück, E. [1 ]
机构：
[1] Fundamental Aspects of Materials and Energy (FAME), Faculty of Applied Science, Delft University of Technology, Mekelweg 15, JB Delft,2629, Netherlands
[2] School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin,541004, China
来源：
Journal of Alloys and Compounds | 2016年 / 625卷
关键词：
Number:; 2012GXNSFGA060002; Acronym:; -; Sponsor: Natural Science Foundation of Guangxi Province; Sponsor:; BASF; FOM; Sponsor: Foundation for Fundamental Research on Matter; 51161005; NSFC; Sponsor: National Natural Science Foundation of China;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
We report on various approaches to control the antiferro-ferromagnetic transition temperature of Mn1.2Co0.8Si0.2P0.8 and related materials for magnetocaloric applications. The effects of the Si substitution, Mn/Co ratio and B addition/substitution on MnCoP have been characterized by X-ray diffraction and magnetic measurements. In each case, these parameters have a great influence on the structural and magnetic properties. Silicon and boron turn out to be the elements suitable to substitute the phosphorous and bring TN closer to room temperature. The study thus paves the way for future tuning of the working temperature and adjustment of the magnetic properties. With entropy change of about 1.4 J kg-1 K-1 for 5 T, the inverse magnetocaloric effect of Mn1.2Co0.8Si0.2P0.8 is modest, but might present some interest for applications other than magnetic cooling. © 2014 Elsevier B.V.
引用
收藏
页码：95 / 100
相关论文
共 50 条
  • [1] Structural, magnetic and magnetocaloric properties of (Mn, Co)2(Si, P) compounds
    Ma, Lei
    Guillou, F.
    Yibole, H.
    Miao, X. F.
    Lefering, A. J. E.
    Rao, G. H.
    Gu, Z. F.
    Cheng, G.
    Bruck, E.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 625 : 95 - 100
  • [2] Synthetic Approach for (Mn,Fe)2(Si,P) Magnetocaloric Materials: Purity, Structural, Magnetic, and Magnetocaloric Properties
    He, Allan
    Svitlyk, Volodymyr
    Mozharivskyj, Yurij
    INORGANIC CHEMISTRY, 2017, 56 (05) : 2827 - 2833
  • [3] Effect of Co and Ni doping on the structure, magnetic and magnetocaloric properties of Fe-rich (Mn,Fe)(2)(P,Si) compounds
    Kiecana, A.
    Batashev, I.
    Dugulan, A. I.
    Kwakernaak, C.
    Pieter, L.
    Zhang, F.
    Van Dijk, N. H.
    Brueck, E.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2022, 561
  • [4] Effect of Co and Ni doping on the structure, magnetic and magnetocaloric properties of Fe-rich (Mn,Fe)2(P,Si) compounds
    Kiecana, A.
    Batashev, I
    Dugulan, A., I
    Kwakernaak, C.
    Pieter, L.
    Zhang, F.
    Van Dijk, N. H.
    Bruck, E.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2022, 561
  • [5] Microstructural and magnetic properties of Mn-Fe-P-Si (Fe2 P-type) magnetocaloric compounds
    Fries, Maximilian
    Pfeuffer, Lukas
    Bruder, Enrico
    Gottschall, Tino
    Ener, Semih
    Diop, Leopold V. S.
    Groeb, Thorsten
    Skokov, Konstantin P.
    Gutfleisch, Oliver
    ACTA MATERIALIA, 2017, 132 : 222 - 229
  • [6] Structural and magnetocaloric properties of (Mn,Fe)2(P,Si) materials with added nitrogen
    Thang, N. V.
    Miao, X. F.
    van Dijk, N. H.
    Bruck, E.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 670 : 123 - 127
  • [7] Effect of M/NM ratios on structural and magnetic properties of (Mn,Fe)2(P, Si) compounds
    Li, C. F.
    Zheng, Z. G.
    Wang, W. H.
    Liu, J. Y.
    Lei, L.
    Zeng, D. C.
    PHYSICA B-CONDENSED MATTER, 2020, 594
  • [8] Drastic Influence of Synthesis Conditions on Structural, Magnetic, and Magnetocaloric Properties of Mn(Fe,Ni)(Si,Al) Compounds
    Nuendute, Balnude
    Hanggai, Wuliji
    Yibole, Hargen
    Tana, Bao
    Tegus, Ojiyed
    Guillou, Francois
    CRYSTALS, 2022, 12 (02)
  • [9] Effect of Si substitution on the Structural, Magnetic and Magnetocaloric Properties of Ni–Mn–In Heusler alloys
    N. Pavan Kumar
    Manvir Singh
    Vishal Mahey
    Suyesh Nautiyal
    D. M. Raj Kumar
    N. V. Rama Rao
    M. Manivel Raja
    Applied Physics A, 2020, 126
  • [10] Magnetocaloric properties of Mn5(Si,P)B2 compounds for energy harvesting applications
    Ojiyed, Hamutu
    van den Berg, Maarten
    Batashev, Ivan
    Shen, Qi
    van Dijk, Niels
    Bruck, Ekkes
    JOURNAL OF ALLOYS AND COMPOUNDS, 2024, 978
12345