Tunable luminescence of Ca12Al14O32F2:Eu2+, Eu3+ phosphors prepared by combustion method

被引:0
|
作者
Chen C.-H. [1 ]
Peng H.-L. [1 ]
Liang L.-F. [1 ]
Meng L.-L. [1 ]
Zhang L.-X. [1 ]
机构
[1] College of Chemistry and Materials Science, Guangxi Teachers Education University, Nanning
来源
Liang, Li-Fang (13607811964@163.com) | 2016年 / Editorial Office of Chinese Optics卷 / 37期
关键词
Ca[!sub]12[!/sub]Al[!sub]14[!/sub]O[!sub]32[!/sub]F[!sub]2[!/sub; Combustion method; Eu[!sup]3+[!/sup; Eu[!sup]2+[!/sup; Phosphor;
D O I
10.3788/fgxb20163708.0932
中图分类号
学科分类号
摘要
A series of luminescent emission-tunable phosphors Ca12Al14O32F2: xEu were synthesized by combustion method. X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) and photoluminescence spectra (PL) were used to characterize the phosphors. The effects of combustion temperature, ammonium fluoride, urea, boric acid and co-activator Eu3+-Eu2+ on the luminescent properties of the phosphors were also studied. The results show that the emission color of the prepared phosphors can be tuned appropriately from orange red to blue by adjusting the synthesis condition due to the coexistence of Eu3+ and Eu2+. © 2016, Science Press. All right reserved.
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页码:932 / 939
页数:7
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  • [1] Yu R.J., Wang J., Zhao Z., Et al., Structure and tunable blue-white-red luminescence of Eu<sup>2+</sup>/Eu<sup>3+</sup>-doped Na<sub>5</sub>Al(PO<sub>4</sub>)<sub>2</sub>F<sub>2</sub> single-phase phosphor, Mater. Lett., 160, pp. 294-297, (2015)
  • [2] Zhang J.C., Long Y.Z., Zhang H.D., Et al., Eu<sup>2+</sup>/Eu<sup>3+</sup>-emission-ratio-tunable CaZr(PO<sub>4</sub>)<sub>2</sub>:Eu phosphors synthesized in air atmosphere for potential white light-emitting deep UV LEDs, J. Mater. Chem. C, 2, 2, pp. 312-318, (2014)
  • [3] Pei Z., Zeng Q., Su Q., A study on the mechanism of the abnormal reduction of Eu<sup>3+</sup>→Eu<sup>2+</sup> in Sr<sub>2</sub>B<sub>5</sub>O<sub>9</sub>Cl prepared in air at high temperature, J. Solid State Chem., 145, 1, pp. 212-215, (1999)
  • [4] Hou J.S., Jiang W.Z., Fang Y.Z., Et al., Red, green and blue emissions coexistence in white-light-emitting Ca<sub>11</sub>(SiO<sub>4</sub>)<sub>4</sub>(BO<sub>3</sub>)<sub>2</sub>:Ce<sup>3+</sup>, Eu<sup>2+</sup>, Eu<sup>3+</sup> phosphor, J. Mater. Chem. C, 1, 37, pp. 5892-5898, (2013)
  • [5] Xu S.C., Li P.L., Wang Z.J., Et al., Luminescence and energy transfer of Eu<sup>2+</sup>/Tb<sup>3+</sup>/Eu<sup>3+</sup> in LiBaBO<sub>3</sub> phosphors with tunable-color emission, J. Mater. Chem. C, 3, 35, pp. 9112-9121, (2015)
  • [6] Xia Z.G., Zhuang J.Q., Liao L.B., Novel red-emitting Ba<sub>2</sub>Tb(BO<sub>3</sub>)<sub>2</sub>Cl:Eu phosphor with efficient energy transfer for potential application in white light-emitting diodes, Inorg. Chem., 51, 13, pp. 7202-7209, (2012)
  • [7] Sokolnicki J., Zych E., Synthesis and spectroscopic investigations of Sr<sub>2</sub>Y<sub>8</sub>(SiO<sub>4</sub>)<sub>6</sub>O<sub>2</sub>:Eu<sup>2+</sup>, Eu<sup>3+</sup> phosphor for white LEDs, J. Lumin., 158, pp. 65-69, (2015)
  • [8] Chen X., Zhao J.F., Yu L.P., Et al., A white light emitting phosphor Sr<sub>1.5</sub>Ca<sub>0.5</sub>SiO<sub>4</sub>:Eu<sup>3+</sup>, Tb<sup>3+</sup>, Eu<sup>2+</sup> for LED-based near-UV chip: preparation, characterization and luminescent mechanism, J. Lumin., 131, 12, pp. 2697-2702, (2011)
  • [9] Dai W.B., Mechanism of the reduction and energy transfer between Eu<sup>2+</sup> and Eu<sup>3+</sup> in Eu-doped CaAl<sub>2</sub>Si<sub>2</sub>O<sub>8</sub> materials prepared in air, J. Mater. Chem. C, 2, 20, pp. 3951-3959, (2014)
  • [10] Dobrowolska A., Zych E., Spectroscopic characterization of Ca<sub>3</sub>Y<sub>2</sub>Si<sub>3</sub>O<sub>12</sub>:Eu<sup>2+</sup>, Eu<sup>3+</sup> powders in VUV-UV-Vis region, J. Phys. Chem. C, 116, 48, pp. 25493-25503, (2012)